Ligand Field Theory and Its Applications

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9780471317760: Ligand Field Theory and Its Applications
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A complete, up-to-date treatment of ligand field theory and itsapplications Ligand Field Theory and Its Applications presents anup-to-date account of ligand field theory, the model currently usedto describe the metal-ligand interactions in transition metalcompounds, and the way it is used to interpret the physicalproperties of the complexes. It examines the traditionalelectrostatic crystal field model, still widely used by physicists,as well as covalent approaches such as the angular overlap model,which interprets the metal ligand interactions using parametersrelating directly to chemical behavior.

Written by internationally recognized experts in the field, thisbook provides a comparison between ligand field theory and moresophisticated treatments as well as an account of the methods usedto calculate the energy levels in compounds of the transitionmetals. It also covers physical properties such as stereochemistry,light absorption, and magnetic behavior. An emphasis on theinterpretation of experimental results broadens the book's field ofinterest beyond transition metal chemistry into the many otherareas where these metal ions play an important role.

As clear and accessible as Brian Figgis's 1966 classic Introductionto Ligand Fields, this new book provides inorganic and bioinorganicchemists as well as physical chemists, chemical physicists, andspectroscopists with a much-needed overview of the many significantchanges that have taken place in ligand field theory over the past30 years.

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About the Author:

BRIAN N. FIGGIS, DSc, is Professor of Inorganic Chemistry at theUniversity of Western Australia.

MICHAEL A. HITCHMAN, DSc, is Reader in Chemistry at the Universityof Tasmania.

Review:

"Figgis and Hitchman have done an excellent job of bringing an oldclassic up-to-date and making it very usable for upper-divisionundergraduates...and for graduate students and faculty."(Choice, Vol. 38, No. 7, March 2001)

"...[the authors] explain how it [Ligand field theory] is usedto interpret the physical properties of the complexes." andfaculty." (SciTech Book News, March 2001)

"...serves its purpose with clarity." (Aslib Book Guide,July 2000)

"...a thoroughly re-worked version of an excellentbook...excellent as an advanced undergraduate or introductorygraduate level course in inorganic chemistry and as a resource forgraduate students..." (Journal of Molecular GraphicsModelling, Vol. 19, No. 6, 2001)

"...a well balanced, practical, and readable monograph on anattractive area of inorganic chemistry." (Angewandte ChemieInternational Edition, Vol. 40 No. 10)

"...thoroughly recommended...an excellent addition to theliterature..." (Journal of Chemical Education, Vol. 79, No.9, September 2002)

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9788126528455: Ligand Field Theory And Its Applications (Special Topics In Inorganic Chemistry)

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