Organic Structures from Spectra - Hardcover

Sternhell, Sev; Kalman, John R.

Hardcover

ISBN 10: 0471906441 ISBN 13: 9780471906445

Publisher: Wiley–Blackwell, 1986

Synopsis

The derivation of structural information from spectroscopic data is now an integral part of organic chemistry courses at all universities. The critical part of any such course is a suitable set of problems to develop the student's understanding of how structures are derived. This book combines the subject matter of a minimal course needed to understand the major spectroscopic techniques with a carefully selected set of 115 problems and 16 problems specifically dealing with the interpretation of proton NMR spectra. The book provides a graded set of problems to develop and consolidate the student's understanding of organic spectroscopy. The accompanying text indicates the level of theory required to tackle the problems. The examples themselves have been carefully selected to include all important structural features and to emphasize connectivity arguments. Some of the compounds were synthesized specifically for this purpose. There are many more easy problems than in other collections. Strenuous efforts have been made to ensure that solutions of the 115 structural problems are unambiguous. Another usual feature is the inclusion of the 16 problems dealing with the interpretation of first-order coupling patterns in proton NMR spectra.

About this title

Review

"...a most exciting compilation...to be recommended and will certainly become a staple of spectroscopic challenges on my shelf." ( Journal of Chemical Education, Vol. 79, October 2002)

From the Back Cover

The derivation of structural information from spectroscopic data is now an integral part of organic chemistry courses at all Universities. A critical part of any such course is a suitable set of problems to develop the student s understanding of how structures are determined from spectra.

Organic Structures from Spectra, FourthEditionis a carefully chosen set of more than 280 structural problems employing the major modern spectroscopic techniques, a selection of 18 problems using 2D–NMR spectroscopy, more than 20 problems specifically dealing with the interpretation of spin–spin coupling in proton NMR spectra and 8 problems based on the quantitative analysis of mixtures using proton and carbon NMR spectroscopy. All of the problems are graded to develop and consolidate the student s understanding of organic spectroscopy. The accompanying text is descriptive and only explains the underlying theory at a level which is sufficient to tackle the problems. The text includes condensed tables of characteristic spectral properties covering the frequently encountered functional groups.

The examples themselves have been selected to include all important structural features and to emphasise connectivity arguments. Many of the compounds were synthesised specifically for this purpose. There are many more easy problems, to build confidence and demonstrate basic principles, than in other collections. 

The fourth edition of this popular textbook:

• now incorporates a suite of new problems dealing with the analysis of 2D NMR spectra (COSY, NOESY, TOCSY and C H Correlation spectroscopy);
• has been expanded and updated to reflect the new developments in the area;
• has an additional 25 carefully selected basic problems;
• provides a set of problems dealing specifically with the quantitative analysis of mixtures using NMR spectroscopy;
• features proton NMR spectra obtained at 200, 400 and 600 MHz and 13C NMR spectra include DEPT experiments as well as proton–coupled experiments;
• conatins 6 problems in the style of the experimental section of a research paper and the appendix contains examples of fully worked solutions.

Organic Structures from Spectra, Fourth Edition will prove invaluable for students of Chemistry, Pharmacy and Biochemistry taking a first course in Organic Chemistry.

Review from earlier edition

" I would definitely state that this book is the most useful aid to basic organic spectroscopy teaching in existence and I would strongly recommend every instructor in this area to use it either as a source of examples or as a class textbook."
Magnetic Resonance in Chemistry

Edition details

• Publisher: Wiley–Blackwell
• Publication date: 1986
• Language: English
• ISBN 10: 0471906441
• ISBN 13: 9780471906445
• Binding: Hardcover
• Number of pages: 212