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Introduces a new, simplified classification for stereoselective reactions based on changes in the number of chiral centres taking place, emphasizing the three-dimensional representations of transition states in which stereoselectivity is determined. Using stereochemical vocabulary in accordance with IUPAC rules, it covers analysis of factors in which asymmetric induction occurs, the interplay between steric and electronic effects, the importance of conformational control, advantages of intramolecularity and the majority of important reaction types used in modern stereoselective synthesis.
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Stereoselective Synthesis considers the methods available for thesynthesis of simple target molecules, the majority containing notmore than two chiral centres, as single stereoisomers. This volumefocuses on the factors which give rise to the stereoselectivity andclassifies stereoselective reactions accordingly. Thisclassification, and the extensive use of 3-D representations,enables the student to understand the stereochemistry of thesereactions and hence apply them to the synthesis of previouslyunseen target molecules as single stereoisomers. StereoselectiveSynthesis presents:
* a new, unique, simplified classification for stereoselectivereactions based on the number of chiral centres created in theproduct by comparison with the number present in the startingmaterial
* coverage of the majority of important reaction types used inmodern stereoselective synthesis
* a detailed analysis of factors which bring about asymmetricinduction: the interplay between steric and electronic effects, theimportance of conformational control and the advantages ofintramolecularity in reactions
* emphasis on synthesis of simple target molecules and on thosesteps which involve stereochemistry
* realistic 3-D representations of transition states in whichstereoselectivity is created
* stereochemical vocabulary in accordance with IUPAC rules
Stereoselective Synthesis is an invaluable aid not only to studentsin understanding this important area but also to those activelyengaged in the syntheses of target molecules as singlestereoisomers.
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Book Description Wiley, 1995. Paperback. Condition: New. Seller Inventory # DADAX0471954195
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