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The Chemistry of Rotational Isomers (Reactivity and Structure: Concepts in Organic Chemistry, 30) - Hardcover
Rotation about the Carbon-Carbon single bond is generally regarded to be unrestricted. About 50 years ago, rotational isomers were found to exhibit optical activity: substituted biphenyl derivatives. However, the author has investigated other classes of compounds that have stable rotational isomers at room temperature. These compounds can serve as models for studying very weak intermolecular interactions, that are difficult to observe. Even diastereotopic groups show different chemical reactivity. From the contents: The "Free Rotation Concept" - Rotamer Populations - Barriers to Rotation - Reactivity of Rotational Isomers.
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- PublisherSpringer
- Publication date1993
- ISBN 10 3540561935
- ISBN 13 9783540561934
- BindingHardcover
- Edition number1
- Number of pages182
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The Chemistry of Rotational Isomers (Reactivity & Structure: Concepts in Organic Chemistry)
Published by
Springer-Verlag Berlin and Heidelberg GmbH & Co. K
(1993)
ISBN 10: 3540561935
ISBN 13: 9783540561934
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Hardcover
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