The Chemistry of Rotational Isomers (Reactivity and Structure: Concepts in Organic Chemistry)

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9783642510267: The Chemistry of Rotational Isomers (Reactivity and Structure: Concepts in Organic Chemistry)
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Rotation about the Carbon-Carbon single bond is generally regarded to be unrestricted. About 50 years ago, rotational isomers were found to exhibit optical activity: substituted biphenyl derivatives. However, the author has investigated other classes of compounds that have stable rotational isomers at room temperature. These compounds can serve as models for studying very weak intermolecular interactions, that are difficult to observe. Even diastereotopic groups show different chemical reactivity. From the contents: The "Free Rotation Concept" - Rotamer Populations - Barriers to Rotation - Reactivity of Rotational Isomers.

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Other Popular Editions of the Same Title

9780387561936: The Chemistry of Rotational Isomers (Reactivity & Structure)

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ISBN 10:  0387561935 ISBN 13:  9780387561936
Publisher: Springer Verlag, 1993
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9783540561934: The Chemistry of Rotational Isomers (Reactivity and Structure: Concepts in Organic Chemistry)

Springer, 1993
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Book Description Springer. Paperback. Condition: New. 172 pages. Dimensions: 9.2in. x 6.1in. x 0.4in.Rotation about the Carbon-Carbon single bond is generally regarded to be unrestricted. About 50 years ago, rotational isomers were found to exhibit optical activity: substituted biphenyl derivatives. However, the author has investigated other classes of compounds that have stable rotational isomers at room temperature. These compounds can serve as models for studying very weak intermolecular interactions, that are difficult to observe. Even diastereotopic groups show different chemical reactivity. From the contents: The Free Rotation Concept - Rotamer Populations - Barriers to Rotation - Reactivity of Rotational Isomers. This item ships from multiple locations. Your book may arrive from Roseburg,OR, La Vergne,TN. Paperback. Seller Inventory # 9783642510267

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Book Description Springer-Verlag Berlin and Heidelberg GmbH & Co. KG, Germany, 2012. Paperback. Condition: New. Language: English. Brand new Book. Rotation about the Carbon-Carbon single bond is generallyregarded to be unrestricted. About 50 years ago, rotationalisomers were found to exhibit optical activity: substitutedbiphenyl derivatives. However, the author has investigatedother classes of compounds that have stable rotationalisomers at room temperature. These compounds can serve asmodels for studying very weak intermolecular interactions,that are difficult to observe. Even diastereotopic groupsshow different chemical reactivity.From the contents: The "Free Rotation Concept" - RotamerPopulations - Barriers to Rotation - Reactivity ofRotational Isomers. Softcover reprint of the original 1st ed. 1993. Seller Inventory # AAV9783642510267

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