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The Anomeric Effect and Related Stereoelectronic Effects at Oxygen (Reactivity and Structure: Concepts in Organic Chemistry) - Softcover

 
9783642686788: The Anomeric Effect and Related Stereoelectronic Effects at Oxygen (Reactivity and Structure: Concepts in Organic Chemistry)
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The anomeric effect is a well-defined and much studied example of a deep­ seated and very general effect in organic chemistry. It involves a fundamental interaction between the lone pair electrons of oxygen and the antibonding orbitals of adjacent bonds, which can control not only conformation but also reactivity in suitable systems. So the heart of this book is a consideration of the properties of non-bonding pairs of electrons, and the influence of orbital­ orbital interactions on structure and reactivity. I have been lucky in recent months to be able to discuss various matters arising in this book with people who know more about them than I do. Parti­ cularly Professors C. Altona, A. Eschenmoser, F. Hirshfeld, M. Lahav, R.A. McClelland, G.M. Sheldrick and A. Vos, and, nearer horne, I. Fleming, P.G. Jones, AJ. Stone (who helped with the rather theoretical Appendix) and I.H. Williams. I am also most grateful to Professors P. Deslongchamps, ID. Dunitz, D.G. Gorenstein, W.P. Jencks, G.A. Jeffrey, R.D. Lemieux and S. Wolfe, for very helpful correspondence, and information in advance of pUblication. I have covered the literature received in Cambridge up to early December 1981.

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  • PublisherSpringer
  • Publication date2012
  • ISBN 10 3642686788
  • ISBN 13 9783642686788
  • BindingPaperback
  • Number of pages160

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9783540116844: The Anomeric Effect and Related Stereoelectronic Effects at Oxygen (Reactivity and Structure: Concepts in Organic Chemistry)

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Publisher: Springer, 1982
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Book Description Taschenbuch. Condition: Neu. This item is printed on demand - it takes 3-4 days longer - Neuware -The anomeric effect is a well-defined and much studied example of a deep seated and very general effect in organic chemistry. It involves a fundamental interaction between the lone pair electrons of oxygen and the antibonding orbitals of adjacent bonds, which can control not only conformation but also reactivity in suitable systems. So the heart of this book is a consideration of the properties of non-bonding pairs of electrons, and the influence of orbital orbital interactions on structure and reactivity. I have been lucky in recent months to be able to discuss various matters arising in this book with people who know more about them than I do. Parti cularly Professors C. Altona, A. Eschenmoser, F. Hirshfeld, M. Lahav, R.A. McClelland, G.M. Sheldrick and A. Vos, and, nearer horne, I. Fleming, P.G. Jones, AJ. Stone (who helped with the rather theoretical Appendix) and I.H. Williams. I am also most grateful to Professors P. Deslongchamps, ID. Dunitz, D.G. Gorenstein, W.P. Jencks, G.A. Jeffrey, R.D. Lemieux and S. Wolfe, for very helpful correspondence, and information in advance of pUblication. I have covered the literature received in Cambridge up to early December 1981. 164 pp. Englisch. Seller Inventory # 9783642686788

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Book Description Taschenbuch. Condition: Neu. Druck auf Anfrage Neuware - Printed after ordering - The anomeric effect is a well-defined and much studied example of a deep seated and very general effect in organic chemistry. It involves a fundamental interaction between the lone pair electrons of oxygen and the antibonding orbitals of adjacent bonds, which can control not only conformation but also reactivity in suitable systems. So the heart of this book is a consideration of the properties of non-bonding pairs of electrons, and the influence of orbital orbital interactions on structure and reactivity. I have been lucky in recent months to be able to discuss various matters arising in this book with people who know more about them than I do. Parti cularly Professors C. Altona, A. Eschenmoser, F. Hirshfeld, M. Lahav, R.A. McClelland, G.M. Sheldrick and A. Vos, and, nearer horne, I. Fleming, P.G. Jones, AJ. Stone (who helped with the rather theoretical Appendix) and I.H. Williams. I am also most grateful to Professors P. Deslongchamps, ID. Dunitz, D.G. Gorenstein, W.P. Jencks, G.A. Jeffrey, R.D. Lemieux and S. Wolfe, for very helpful correspondence, and information in advance of pUblication. I have covered the literature received in Cambridge up to early December 1981. Seller Inventory # 9783642686788

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Book Description Condition: New. Dieser Artikel ist ein Print on Demand Artikel und wird nach Ihrer Bestellung fuer Sie gedruckt. A. Stereoelectronic Effects on Structure.- 1. Introduction.- 2. The Anomeric Effect.- 3. The Reverse Anomeric Effect.- 4. The Exo-Anomeric Effect.- 5. The Generalised Anomeric Effect.- a. Sulphur Compounds.- b. Transmission through Phosphorus.- c. Transmiss. Seller Inventory # 5068095

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