Activated Metals in Organic Synthesis

Cintas, Pedro

Published by Taylor and Francis, 1993
ISBN 10: 084937863X / ISBN 13: 9780849378638
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Synopsis: Activated Metals in Organic Synthesis discusses fundamental principles of the generation of activated, highly reactive metals, and their applications in organic synthesis. Following an introductory chapter on basic forms of metals the chapters in Part 1 are devoted to common strategies utilized for the preparation of active metals. These strategies include vaporization and subsequent co-condensation of metal atoms, in addition to depassivating methods employed commonly in laboratory syntheses. Chapters in Part 2 discuss relevant organic transformations in which metal activation plays a crucial role. Specific topics covered include metal-induced reductive methods; pinacolic, Reformatsky-, and Barbier-type reactions; McMurry ketone-olefin coupling; and the Bernet-Vasella reaction. Each chapter is followed by literature citations ranging from specific references to significant reviews. Many structural formulas are provided, making it easy to follow each synthesis. The book will be an important reference for students, organic chemists, and researchers in all areas of organometallic chemistry.

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Title: Activated Metals in Organic Synthesis
Publisher: Taylor and Francis
Publication Date: 1993
Binding: HRD
Book Condition: New

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Book Description CRC Press, Boca Raton Florida USA, 1993. Grey and Green Boards. Condition: Very good. No Jacket. Part One: Metal Activation comprises: Basic Forms of Metals; Metal Vapor Chemistry; Depassivating Methods. Part Two Metal-Mediated Reactions comprises: Reductions; Reductive Carbonyl Coupling Reactions; Additional Reactions to Carbonyl Compounds; Cyclizations; The Bernet-Vasella Reaction. 236 p. Very slight rubbing to the extremities. Cut edges, pages and actual text are very clean and unmarked. Size: 6 1/4 " x 9 1/2 ". Hard Cover. Seller Inventory # 0007056

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Book Description Taylor Francis Inc, United States, 1993. Hardback. Condition: New. Language: English . Brand New Book. Activated Metals in Organic Synthesis discusses fundamental principles of the generation of activated, highly reactive metals, and their applications in organic synthesis. Following an introductory chapter on basic forms of metals the chapters in Part 1 are devoted to common strategies utilized for the preparation of active metals. These strategies include vaporization and subsequent co-condensation of metal atoms, in addition to depassivating methods employed commonly in laboratory syntheses. Chapters in Part 2 discuss relevant organic transformations in which metal activation plays a crucial role. Specific topics covered include metal-induced reductive methods; pinacolic, Reformatsky-, and Barbier-type reactions; McMurry ketone-olefin coupling; and the Bernet-Vasella reaction. Each chapter is followed by literature citations ranging from specific references to significant reviews. Many structural formulas are provided, making it easy to follow each synthesis. The book will be an important reference for students, organic chemists, and researchers in all areas of organometallic chemistry. Seller Inventory # AA69780849378638

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