Macromolecular Mechanochemistry Vol. ol. One (P Part art I & P Part art II): Polymer Mechanochemistry

Cleopatra Vasiliu-Oprea & Florin Dan

Published by Cambridge International Science Publishing
ISBN 10: 8130909391 / ISBN 13: 9788130909394
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Synopsis: The book is divided into the following sections:
Polystage feature of mechanochemical process
Polymer mechanochemistry deformation
Mechano-degradation
Influence of some factors on mechano-chemical degradation
Effect of mechano-degradation on the structure and properties of polymers
Polymer fracture
Fracture of composite materials

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Title: Macromolecular Mechanochemistry Vol. ol. One...
Publisher: Cambridge International Science Publishing
Binding: PaperBack
Book Condition: Brand New
Edition: International Edition.

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Book Description Viva Books Private Limited, 2008. Hardcover. Book Condition: New. First edition. This two-volume set is an extremely detailed account of all aspects of macromolecular mechanochemistry and will be of great interest to all experts in this area of rapidly advancing mechanochemistry. Mechanochemical transformations are the subject of increasing attention in solid-state chemistry, physics and materials science, as well as in the development of advanced technologies. They have been discussed at a number of symposia on mechanochemistry and mechanical alloying in various countries. Contents: Volume I: CHAIN MULTISTAGE MECHANISM OF THE MECHANOCHEMICAL PROCESS: Bibliography Part I ? MECHANOCHEMISTRY OF POLYMER DEFORMATION: On the local character of polymer deformation; Basis of the theory of local character of deformation; The local character of polymer fracture; Deformation and fracture - interconnected processes ; Mechanochemical mechanism of polymer deformation; Kinetic aspects; Kinetics of the mechanochemical reactions in constant mechanical fields; Mechanochemistry of polymer deformation under creep conditions; Chemical stress relaxation; Mechanocracking of the chemical bonds from the main chain; Mechanism of mechanocracking of chemical bonds from the main chain; Mechanocracking of cross-bridges (transversal bonds); Interchange reactions; Multiple mechanocracking of polymer networks; Scission of the cross-bridges and along the main chains; Reticulation reactions; Applications of chemorheology; Control of thermal stability of polyolefin-type hydrocarbonate networks; Characterisation of some thermosetting networks for varnishes and adhesives; Characterisation of some thermosetting resins; Some aspects of the chemorheology of linear amorphous polymers; Bibliography Part 2 ? MECHANOCHEMISTRY OF POLYMER FRACTURE: Theories concerning polymer fracture; Basis of the theory of the local character of deformation; Griffith?s theory; Kinetic theories of fracture; Generalised theory of polymer fracture. Andrews?s theory; Chemical bond strength; Mechanochemical mechanism of fracture; Irreversible conversion of mechanical energy into chemical energy (The nonequilibrium process); Nature of the primary active centers of mechanochemical reactions; Chained mechanism of macromolecular chain splitting; Initiation; Propagation; Interruption. Stabilization of destruction active fragments; Types of homolytical mechanodegradation mechanism of some usual polymers; Heterolytical mechanism; Kinetics: Factors that influence the mechanodegradation process; Structural factors; Macromolecular chain characteristics; Characteristics of supramolecular-morphological structure; Temperature; Reaction medium; Inert media; Radical acceptors; Organic liquids compatible with the stressed polymer; Mechanical regime; Modification of the structure-properties relationship by polymer degradation and fracture; Modification of the relation between molecular structure and physico-chemical properties of polymers; Modification of the polydispersity-properties relationship; Modification of the relation supramolecular-morphological structure - properties; Physical phenomena that accompany polymer mechanodegradation and fracture; Mechanochemical reactions at fracture surfaces; Mechanochemical synthesis; Mechanochemical polymerisation; Mechanochemical polymerisation of crystalline monomers; Mechanochemical polymerisation initiated by crystalline inorganic compounds; Initiation of mechanochemical polymerisation and copolymeris-ation in the absence of mechanoinitiators; Mechanochemical block copolymerisation and grafting Mechanochemical polycondensation; Factors that affect Mechanoechemical polycondensation; Considerations of the mechanism of Mechanochemical polycondensation; Mechanochemical complexation; Mechanochemical reactions on the surface of polyfunctional acceptors; Bibliography Part III ? Index Volume II: Mechanochemical Reactions Printed Pages: 960. Bookseller Inventory # 4894

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Cleopatra Vasiliu
Published by Viva Books Private Limited (2008)
ISBN 10: 8130909391 ISBN 13: 9788130909394
New Hardcover First Edition Quantity Available: > 20
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Book Description Viva Books Private Limited, 2008. Hardcover. Book Condition: New. First edition. This two-volume set is an extremely detailed account of all aspects of macromolecular mechanochemistry and will be of great interest to all experts in this area of rapidly advancing mechanochemistry. Mechanochemical transformations are the subject of increasing attention in solid-state chemistry, physics and materials science, as well as in the development of advanced technologies. They have been discussed at a number of symposia on mechanochemistry and mechanical alloying in various countries. Contents: Volume I: CHAIN MULTISTAGE MECHANISM OF THE MECHANOCHEMICAL PROCESS: Bibliography Part I ⢠MECHANOCHEMISTRY OF POLYMER DEFORMATION: On the local character of polymer deformation; Basis of the theory of local character of deformation; The local character of polymer fracture; Deformation and fracture - interconnected processes ; Mechanochemical mechanism of polymer deformation; Kinetic aspects; Kinetics of the mechanochemical reactions in constant mechanical fields; Mechanochemistry of polymer deformation under creep conditions; Chemical stress relaxation; Mechanocracking of the chemical bonds from the main chain; Mechanism of mechanocracking of chemical bonds from the main chain; Mechanocracking of cross-bridges (transversal bonds); Interchange reactions; Multiple mechanocracking of polymer networks; Scission of the cross-bridges and along the main chains; Reticulation reactions; Applications of chemorheology; Control of thermal stability of polyolefin-type hydrocarbonate networks; Characterisation of some thermosetting networks for varnishes and adhesives; Characterisation of some thermosetting resins; Some aspects of the chemorheology of linear amorphous polymers; Bibliography Part 2 ⢠MECHANOCHEMISTRY OF POLYMER FRACTURE: Theories concerning polymer fracture; Basis of the theory of the local character of deformation; Griffithâs theory; Kinetic theories of fracture; Generalised theory of polymer fracture. Andrewsâs theory; Chemical bond strength; Mechanochemical mechanism of fracture; Irreversible conversion of mechanical energy into chemical energy (The nonequilibrium process); Nature of the primary active centers of mechanochemical reactions; Chained mechanism of macromolecular chain splitting; Initiation; Propagation; Interruption. Stabilization of destruction active fragments; Types of homolytical mechanodegradation mechanism of some usual polymers; Heterolytical mechanism; Kinetics: Factors that influence the mechanodegradation process; Structural factors; Macromolecular chain characteristics; Characteristics of supramolecular-morphological structure; Temperature; Reaction medium; Inert media; Radical acceptors; Organic liquids compatible with the stressed polymer; Mechanical regime; Modification of the structure-properties relationship by polymer degradation and fracture; Modification of the relation between molecular structure and physico-chemical properties of polymers; Modification of the polydispersity-properties relationship; Modification of the relation supramolecular-morphological structure - properties; Physical phenomena that accompany polymer mechanodegradation and fracture; Mechanochemical reactions at fracture surfaces; Mechanochemical synthesis; Mechanochemical polymerisation; Mechanochemical polymerisation of crystalline monomers; Mechanochemical polymerisation initiated by crystalline inorganic compounds; Initiation of mechanochemical polymerisation and copolymeris-ation in the absence of mechanoinitiators; Mechanochemical block copolymerisation and grafting Mechanochemical polycondensation; Factors that affect Mechanoechemical polycondensation; Considerations of the mechanism of Mechanochemical polycondensation; Mechanochemical complexation; Mechanochemical reactions on the surface of polyfunctional acceptors; Bibliography Part III ⢠Index Volume II: Mechanochemical Reactions Printed Pages: 960. Bookseller Inventory # 4894

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