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Vanadium Polyoxomatelate: An Oxidant for Oxidative Transformation

Anindita Dewan

ISBN 10: 3659510513 / ISBN 13: 9783659510519
Published by LAP LAMBERT Academic Publishing
New Condition: New Soft cover
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76 pages. Dimensions: 8.7in. x 5.9in. x 0.2in.A novel vanadium polyoxometalate (C6H5CH2)(CH3)3N3H3V10O283H2O works as a useful oxidant for selective and rapid oxidation of benzylic alcohols to the corresponding carbonyl compounds in the presence of PTSA under solvent-free, room temperature conditions in excellent yield. The same vanadium polyoxometalate can be applied for the oxidative transformation of variety of aldoxime and ketoxime to the corresponding aldehydes and ketones under solvent less condition at room temperature within a minute. Moreover this vanadium polyoxometalate works as a useful oxidant for the oxidation of thiols to disulfldes in water under mild reaction conditions in an excellent yield. This item ships from multiple locations. Your book may arrive from Roseburg,OR, La Vergne,TN. Bookseller Inventory # 9783659510519

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Bibliographic Details

Title: Vanadium Polyoxomatelate: An Oxidant for ...

Publisher: LAP LAMBERT Academic Publishing

Binding: Paperback

Book Condition:New

Book Type: Paperback

About this title

Synopsis:

A novel vanadium polyoxometalate [(C6H5CH2)(CH3)3N]3[H3V10O28]3H2O works as a useful oxidant for selective and rapid oxidation of benzylic alcohols to the corresponding carbonyl compounds in the presence of PTSA under solvent-free, room temperature conditions in excellent yield. The same vanadium polyoxometalate can be applied for the oxidative transformation of variety of aldoxime and ketoxime to the corresponding aldehydes and ketones under solvent less condition at room temperature within a minute. Moreover this vanadium polyoxometalate works as a useful oxidant for the oxidation of thiols to disulfldes in water under mild reaction conditions in an excellent yield.

About the Author:

Dr Anindita Dewan received her PhD in 2009 under the guidance of Dr. D. K. Kakati at the Department of Chemistry, Gauhati University, Guwahati. She is currently working as DST-Woman Scientist for her postdoctoral research at the Department of Chemistry, Dibrugarh University. She was also a recipient of UGC-Dr D.S. Kothari Postdoctoral Fellowship

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