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Boronic Acids: Preparation, Applications in Organic Synthesis and Medicine - Hardcover

 
9783527309917: Boronic Acids: Preparation, Applications in Organic Synthesis and Medicine
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For the first time, the whole field of organoboronic acids is presented in one comprehensive handbook.
Professor Dennis Hall, a rising star within the community, covers all aspects of this important substance class, including applications in chemistry, biology and medicine.
Starting with an introduction to the structure, properties, and preparation of boronic acid derivatives, together with an overview of their reactions and applications, the book goes on to look at metal-catalyzed borylation of alkanes and arenas, coupling reactions and rhodium-catalyzed additions of boronic acids to alkenes and carbonyl compounds. There follows chapters on copper-promoted C-O and C-N cross-coupling of boronic acids, recent applications in organic synthesis, as well as alpha-haloalkylboronic esters in asymmetric synthesis. Later sections deal with cycloadditions, organoboronic acids, oxazaborolidines as asymmetric inducers, and boronic acid based receptors and sensors. The whole is rounded off with experimental procedures, making this invaluable reading for organic, catalytic and medicinal chemists, as well as those working in organometallics.

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From the Back Cover:
In the past decade, organoboronic acids and boronic esters have become an extremely important class of compounds. Stable and safe to handle, these green compounds embrace a wide range of applications including their use as reagents and catalysts in organic synthesis, as probes and sensors in chemical biology, and as therapeutic drugs. Here, for the first time, the full story of organoboronic acids is presented in one comprehensive handbook. Professor Dennis Hall, a rising star in the field, is joined by a select group of expert authors to provide 13 chapters that cover all modern aspects of boronic acid derivatives. This book is an invaluable reading for organic, organometallic, and medicinal chemists.

From the Contents:

Structure, properties, and preparation of boronic acid derivatives
Metal-catalyzed borylation of alkanes and arenes
Cross-coupling reactions of areneboronic acids or esters with aromatic electrophiles
Rhodium-catalyzed additions of boronic acids to alkenes and carbonyl compounds
Copper-promoted C-heteroatom bond cross-coupling reactions with boronic acids
Preparation of allylboronates and recent applications in organic synthesis
Nucleophilic addition reactions of aryl and alkenylboronic acids to imine derivatives
Alpha-haloalkylboronic esters in asymmetric synthesis
Cycloadditions and other additions to alkenyl- alkynyl-, and dienylboronic esters
Organoboronic acids and organoborinic acids as catalysts in organic synthesis
Oxazaborolidines as asymmetric inducers for the reduction of ketones and ketimines
Boronic acid based receptors and sensors for saccharides
Biological and medicinal applications of boronic acids
About the Author:
Dennis Hall is a Professor of Chemistry at the University of Alberta (Edmonton, Canada). He was born in 1968 in northern Quebec, Canada, and was educated at Université de Sherbrooke, obtaining his Ph.D. in 1995 under the direction of Prof. Pierre Deslongchamps. Hall was an NSERC Postdoctoral Fellow in the laboratory of Prof. Peter G. Schultz in the Department of Chemistry at the University of California, Berkeley, and initiated his independent career in 1997. The unifying theme of his research program is the development of new synthetic and biological applications of organoboronic acid derivatives. Ongoing projects in his laboratory cover a wide range of topics, including stereocontrolled allylation methodology, multicomponent reactions, solid-phase organic synthesis, combinatorial chemistry and oligosaccharide recognition. His recent awards include a Petro-Canada Young Innovator Award (2003), the AstraZeneca Award in Chemistry (2003), and the University of Alberta's Martha Cook Piper Research Prize (2004). He is a Fellow of the Canadian Institute of Chemistry.

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  • PublisherWiley-VCH
  • Publication date2005
  • ISBN 10 3527309918
  • ISBN 13 9783527309917
  • BindingHardcover
  • Edition number1
  • Number of pages571
  • EditorHall Dennis G.

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Published by Wiley-VCH (2005)
ISBN 10: 3527309918 ISBN 13: 9783527309917
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