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Crystallography of the Polymethylene Chain: An Inquiry into the Structure of Waxes (International Union of Crystallography Monographs on Crystallography) - Hardcover
Book 4 of 18: International Union of Crystallography Monographs on Crystallography
Synopsis
By considering the solid state packing of linear chain wax components, this book aims at understanding three things: firstly, which modifications of molecular components are allowed for maintaining stable solid solutions; secondly, what happens when stability conditions are traversed and fractionation begins and thirdly, the structure of fractionated arrays. The co-compatibility of molecular ingredients is considered in terms of their shapes and relative sizes, following an approach originally proposed by Kitaigorodskii. As demonstrated profusely by the crystal structures of pure component types (e. g. alkanes, fatty alcohols, fatty acids, long chain esters, cholesteryl esters) and insertion of functional groups (e. g. chain branches, unsaturation, heteroatoms), characteristic molecular packing arrays provide important geometric information for understanding the co-packing of different molecules in mixtures. Single crystal and spectroscopic data from polydisperse arrays can then be evaluated to arrive at plausible structures of solid solutions and fractionated systems. The resultant structures are not only relevant to the understanding of so-called waxes but also include certain classes of polymers. The ramifications of this work extend into any solid state array of polymethylene chains, including lipid foodstuffs.
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About the Author
Douglas L. Dorset is Senior Research Associate at ExxonMobil Research & Engineering Company in Annandale, New Jersey.
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Crystallography of the Polymethylene Chain (Hardcover)
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ISBN 10: 0198529082
ISBN 13: 9780198529088
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Hardcover. Condition: new. Hardcover. By considering the solid state packing of linear chain wax components, this book aims at understanding three things: firstly, which modifications of molecular components are allowed for maintaining stable solid solutions; secondly, what happens when stability conditions are traversed and fractionation begins and thirdly, the structure of fractionated arrays. The co-compatibility of molecular ingredients is considered in terms of their shapes and relative sizes,following an approach originally proposed by Kitaigorodskii. As demonstrated profusely by the crystal structures of pure component types (e. g. alkanes, fatty alcohols, fatty acids, long chain esters,cholesteryl esters) and insertion of functional groups (e. g. chain branches, unsaturation, heteroatoms), characteristic molecular packing arrays provide important geometric information for understanding the co-packing of different molecules in mixtures. Single crystal and spectroscopic data from polydisperse arrays can then be evaluated to arrive at plausible structures of solid solutions and fractionated systems. The resultant structures are not only relevant to the understanding of so-calledwaxes but also include certain classes of polymers. The ramifications of this work extend into any solid state array of polymethylene chains, including lipid foodstuffs. How do mixtures of differently sized and shaped molecules form the plastic solids known as waxes? Firstly, this book considers the characteristic crystalline assemblies of wax ingredients; secondly, it looks at assemblies of two separate components; and finally, it shows how plausible molecular models for several types of wax can be constructed. This item is printed on demand. Shipping may be from our Sydney, NSW warehouse or from our UK or US warehouse, depending on stock availability. Seller Inventory # 9780198529088
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Crystallography of the Polymethylene Chain: An Inquiry into the Structure of Waxes (International Union of Crystallography Monographs on Crystallography)
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ISBN 10: 0198529082
ISBN 13: 9780198529088
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Crystallography of the Polymethylene Chain: An Inquiry into the Structure of Waxes: 17 (International Union of Crystallography Monographs on Crystallography)
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Condition: New. How do mixtures of differently sized and shaped molecules form the plastic solids known as waxes? Firstly, this book considers the characteristic crystalline assemblies of wax ingredients; secondly, it looks at assemblies of two separate components; and finally, it shows how plausible molecular models for several types of wax can be constructed. Series: International Union of Crystallography - Monographs on Crystallography. Num Pages: 246 pages, numerous line figures and halftones. BIC Classification: PHV; PNNP; PNR; PNT. Category: (P) Professional & Vocational. Dimension: 242 x 163 x 18. Weight in Grams: 569. . 2004. Illustrated. hardcover. . . . . Seller Inventory # V9780198529088
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Crystallography of the Polymethylene Chain: An Inquiry into the Structure of Waxes (eng)
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Crystallography of the Polymethylene Chain (Hardcover)
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ISBN 10: 0198529082
ISBN 13: 9780198529088
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Hardcover. Condition: new. Hardcover. By considering the solid state packing of linear chain wax components, this book aims at understanding three things: firstly, which modifications of molecular components are allowed for maintaining stable solid solutions; secondly, what happens when stability conditions are traversed and fractionation begins and thirdly, the structure of fractionated arrays. The co-compatibility of molecular ingredients is considered in terms of their shapes and relative sizes,following an approach originally proposed by Kitaigorodskii. As demonstrated profusely by the crystal structures of pure component types (e. g. alkanes, fatty alcohols, fatty acids, long chain esters,cholesteryl esters) and insertion of functional groups (e. g. chain branches, unsaturation, heteroatoms), characteristic molecular packing arrays provide important geometric information for understanding the co-packing of different molecules in mixtures. Single crystal and spectroscopic data from polydisperse arrays can then be evaluated to arrive at plausible structures of solid solutions and fractionated systems. The resultant structures are not only relevant to the understanding of so-calledwaxes but also include certain classes of polymers. The ramifications of this work extend into any solid state array of polymethylene chains, including lipid foodstuffs. How do mixtures of differently sized and shaped molecules form the plastic solids known as waxes? Firstly, this book considers the characteristic crystalline assemblies of wax ingredients; secondly, it looks at assemblies of two separate components; and finally, it shows how plausible molecular models for several types of wax can be constructed. This item is printed on demand. Shipping may be from multiple locations in the US or from the UK, depending on stock availability. Seller Inventory # 9780198529088
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Crystallography Of The Polymethylene Chain : An Inquiry Into The Structure Of Waxes
Published by
Oxford University Press, 2005
ISBN 10: 0198529082
ISBN 13: 9780198529088
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