Theoretical and Physical Principles of Organic Reactivity - Hardcover

Pross, Addy

Hardcover

ISBN 10: 0471555991 ISBN 13: 9780471555995

Publisher: Wiley-Interscience, 1995

Synopsis

Traditionally, physical organic chemistry and theoretical organicchemistry have been treated as separate disciplines. This new bookbridges these two areas in order to give the reader a newperspective on the nature of organic reactivity. A key element ofthis new approach is the author's extensive nonmathematicaldescription of the recently developed curve-crossing model thatdescribes why chemical reactions have an activation barrier, andspecifies the factors that govern the barrier heights. In addition,the author draws from physical chemistry and transition-metalchemistry to present an original and detailed description ofelectron transfer theory, and covers the recent discovery that theelectron transfer process is intimately related to many basicorganic processes.

This book has been divided into three parts to facilitate itsmixture of classical organic chemistry with new and establishedtheoretical ideas. Part A presents an introductory description ofmolecular orbital and valence bond theories with emphasis on thequalitative aspects that can be applied to practical problems inorganic structure and reactivity. Part B describes the keyprinciples of physical organic chemistry and incorporates a mainlyqualitative description of the Marcus theory of electrontransfer.

Building on the theoretical framework developed in parts A and B,part C offers an overview of the basic reactions of organicchemistry: nucleophilic and electrophilic substitution, and radicaland pericyclic reactivity. In addition, part C clearly explains themost recent unifying description of organic reactivity for organicchemists and for graduate and advanced undergraduate students.

About this title

About the Author

ADDY PROSS is Professor of Chemistry at Ben Gurion University of the Negev, Beer-Sheva, Israel, and an Australian Research Council Senior Research Fellow at the University of Sydney, Australia. Professor Pross received his PhD in organic chemistry from the University of Sydney.

From the Back Cover

Traditionally, physical organic chemistry and theoretical organic chemistry have been treated as separate disciplines. This new book bridges these two areas in order to give the reader a new perspective on the nature of organic reactivity. A key element of this new approach is the author's extensive nonmathematical description of the recently developed curve-crossing model that describes why chemical reactions have an activation barrier, and specifies the factors that govern the barrier heights. In addition, the author draws from physical chemistry and transition-metal chemistry to present an original and detailed description of electron transfer theory, and covers the recent discovery that the electron transfer process is intimately related to many basic organic processes.

This book has been divided into three parts to facilitate its mixture of classical organic chemistry with new and established theoretical ideas. Part A presents an introductory description of molecular orbital and valence bond theories with emphasis on the qualitative aspects that can be applied to practical problems in organic structure and reactivity. Part B describes the key principles of physical organic chemistry and incorporates a mainly qualitative description of the Marcus theory of electron transfer.

Building on the theoretical framework developed in parts A and B, part C offers an overview of the basic reactions of organic chemistry: nucleophilic and electrophilic substitution, and radical and pericyclic reactivity. In addition, part C clearly explains the most recent unifying description of organic reactivity for organic chemists and for graduate and advanced undergraduate students.

This book has been divided into three parts to facilitate its mixture of classical organic chemistry with new and established theoretical ideas. Part A presents an introductory description of molecular orbital and valence bond theories with emphasis on the qualitative aspects that can be applied to practical problems in organic structure and reactivity. Part B describes the key principles of physical organic chemistry and incorporates a mainly qualitative description of the Marcus theory of electron transfer.

Building on the theoretical framework developed in parts A and B, part C offers an overview of the basic reactions of organic chemistry: nucleophilic and electrophilic substitution, and radical and pericyclic reactivity. In addition, part C clearly explains the most recent unifying description of organic reactivity for organic chemists and for graduate and advanced undergraduate students.

Edition details

• Publisher: Wiley-Interscience
• Publication date: 1995
• Language: English
• ISBN 10: 0471555991
• ISBN 13: 9780471555995
• Binding: Hardcover
• Edition number: 1
• Number of pages: 312