Matrix Isolation: A Technique for the Study of Reactive Inorganic Species - Hardcover

Cradock, Stephen; Hinchcliffe, A. J.

Hardcover

ISBN 10: 0521207592 ISBN 13: 9780521207591

Publisher: Cambridge University Press, 1975

Synopsis

Many chemical species are too reactive under normal conditions to allow normal spectroscopic investigation. The technique of matrix isolation was developed to exploit the stabilisation that arises when the reactive species is physically trapped, restricting its freedom of movement and access to possible reaction partners. The use of cryogenic conditions to achieve the physical trapping brought valuable consequences in reducing the energy available to the species, meaning they can be studies using a variety of spectroscopic techniques. In simple terms the technique involves trapping a reactive species in a frozen cage, or matrix, of an inert medium such as a rare gas or in other situations nitrogen or carbon monoxide. This 1975 book shows how and why the technique developed and describes the necessary apparatus in some detail, showing how each of the technological problems may be overcome.

About this title

Book Description

In simple terms matrix isolation involves trapping a reactive species in a frozen cage, or matrix, of an inert medium such as a rare gas. This 1975 book shows how and why the technique developed and describes the necessary apparatus, showing how each of the technological problems may be overcome.

Edition details

• Publisher: Cambridge University Press
• Publication date: 1975
• ISBN 10: 0521207592
• ISBN 13: 9780521207591
• Binding: Hardcover
• Language: English
• Number of pages: 151