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Concepts in Transition Metal Chemistry ISBN 13: 9781849730600

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9781849730600: Concepts in Transition Metal Chemistry

Synopsis

Metals play a vital role in the metabolism of plants and animals and, increasingly, in medicine. This book, one of two used as the main teaching material on an Open University course, provides an introduction to the transition metals, examining the behaviour of the metals and their aqueous ions and complexes. The first four chapters provide an introduction to the transition metals, coordination chemistry, stereochemistry and isomerisms and ligands. The fifth chapter introduces the d orbitals in transition metal complexes and then moves on to crystal-field theory. Finally in the last chapter, the disparate properties of magnetism, spectra and bonding are brought together with one unifying theory, in molecular orbital theory. The publication comes complete with The Periodic Table DVD.

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From the Back Cover

The chemistry of the transition metals is a vital part of undergraduate courses in inorganic chemistry and is an essential background for bioinorganic chemistry. This teaching text, together with the accompanying Periodic Table DVD-ROM, provides an introduction to the transition metals, examining the behaviour of the metals and their aqueous ions and complexes. The book begins, largely using interactive activities and video on the DVD, by introducing the reader to the chemistry of the first-row transition elements in different oxidation states, in particular +2 and +3, and their relative stability. This is followed by a study of coordination chemistry. Later chapters look at theories of metal-ligand bonding and the way models can be used to rationalise many of the properties of transition metals and their compounds, such as colour, magnetism and stereochemistry. Starting with the simple, yet powerful crystal-field approach, the book finishes with a largely pictorial treatment of molecular orbital theory. (A basic knowledge of atomic and molecular orbitals as applied to the main-Group elements is assumed.) The material in this book is designed to be used either as part of an undergraduate chemistry programme, or for self-directed study. Learning is facilitated through various key features, including: " interactive activities on the accompanying Periodic Table DVD " in-text questions with answers " full-colour diagrams " revision exercises on an associated website (www.rsc.org/metalsandlife) This book was written as part of the teaching material for the Open University course, S347 Metals and Life. An associated book, Metals and Life also published by RSC Publishing, explores the vital role that metals play in the physiology of animals and plants, and increasingly in medicine.

About the Author

Eleanor Crabb is a Lecturer in materials chemistry at The Open University and was recently seconded part-time to one of the Centres for Excellence in Teaching and Learning (CETL) awarded to The Open University. Her research interests are in heterogeneous catalysis. She has written on a number of science courses, producing both text based and multimedia materials, including Separation, Purification and Identification, part of the Molecular World Series (a collection of OU undergraduate texts also published by the RSC). Rob Janes is a Staff Tutor at The Open University in Wales. He has co-authored the Elements of the p-block in the Molecular World Series and has produced a CD-ROM-database of chemical demonstrations to accompany the book. Together with Elaine Moore, he was also a co-author of Metal-ligand bonding, another RSC publication. He is a co-presenter of Magic Molecules, a demonstration lecture aimed at schools and the general public. David Johnson is a Visiting Reader in chemistry at The Open University. He was a founding member of the Department and worked on many of the chemistry courses writing a number of copublished texts including Metals and chemical change and Elements of the p Block, part of the Molecular World Series. Elaine Moore is Reader in theoretical chemistry at The Open University. Her research interests lie in the field of computational chemistry. She is the author of OU teaching texts in chemistry, physics and astronomy, including Molecular Modelling and Bonding, in the Molecular World Series, and Metal-ligand bonding. Lesley Smart is a Visiting Senior Lecturer in chemistry at The Open University. She has written on many science courses and chaired the production of the Molecular World Series. She is also an author of two books in the series' The Third Dimension and Separation, Purification and Identification.

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