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Щелочное нитробензольное окисление лигнина в химии древесины: Достижения и перспективы (Russian Edition) - Softcover

 
9783847390640: Щелочное нитробензольное окисление лигнина в химии древесины: Достижения и перспективы (Russian Edition)
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V monografii rassmotren metod shchelochnogo nitrobenzol'nogo okisleniya lignina. Obobshcheny literaturnye dannye i razrabotannye avtorom modifikatsii metoda shchelochnogo NBO dlya analiza nativnogo lignina drevesiny i tekhnicheskikh ligninov. Rassmotreny varianty kataliticheskogo NBO s ispol'zovaniem razlichnykh gomogennykh katalizatorov – antrakhinona, orto-fenantrolina, polietilenglikolya i stabilizirovannogo polisul'fida. Issledovan mekhanizm vzaimodeystviya lignina i NB v shchelochnoy srede, vydvinuta novaya kontseptsiya mekhanizma vzaimodeystviya lignina i nitrobenzola. Predlozheny soedineniya, potentsial'no sposobnye effektivno zamenit' NB. Pokazana vozmozhnost' sinteza zameniteley nitrobenzola iz tekhnicheskikh ligninov. Obnaruzhena vozmozhnost' povysheniya vykhoda al'degidov pri osushchestvlenii protsessa NBO v srede kataliticheski okislennykh belykh sul'fatnykh shchelokov. Ustanovleno, chto sintezirovannye iz tekhnicheskikh ligninov zameniteli NB effektivny kak mediatory pri okislenii lignina do aromaticheskikh al'degidov kislorodom. Ill.4, tabl.25, bibliogr. 133 nazv.

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Dokt.khim.nauk.,prof., zakonchil khim. fakul'tet Irkutskogo gosudarstvennogo universiteta v 1973 g. v 1984 g. zashchitil kand. diss., v 1998 - dokt. diss., Spetsialist v oblasti khimii drevesiny i neftekhimicheskikh proizvodstv.V nastoyashchee vremya - st.n.s. Irkutskogo instituta khimii SO RAN, professor Irkutskogo Gosudarstvennogo Tekhnicheskogo Universiteta.

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