Title: Active Sties of Polymerization : Multiplicity: Stereospecific And Kinetic Heterogeneity
Publisher: CRC Press
Publication Date: 2005
Language: English
ISBN 10: 9067644242
ISBN 13: 9789067644242
Binding: Hardcover
Condition: New

About this title

Synopsis

The monograph is intended to systematize data on active sites and their kinetic and stereospecific heterogeneity (polysite phenomenon) in olefin and diene monomer ion, ion-coordination and complex radical polymerization processes. Questions of molecular-mass distribution of polymers obtained by ion and ion-coordination polymerization methods are discussed together with composition and stereo regularity distribution of olefin copolymers. Data on the influence of transition and non-transition metal origin and their ligand ambience, conditions of catalytic system preparation and polymerization are shown. Various assessment methods of polymerization active site distribution by kinetic activity and stereospecific action are considered. In particular, an assessment method for kinetic activity distribution at ion-coordination diene polymerization is described, mathematical simulation parameters for polymerization processes are shown, taking into account the polysite structure of catalytic systems. Of special attention are geometrical and electron structure of active sites in the ion-coordination polymerization by the quantum chemistry method, interrelation between reactivity of some types of active sites and stereospecificity of their action in diene polymerization. The importance of ratio between specific time elementary act duration at the diene injection, coordinated on an active site, and time of propagating macrochain end unit existence in the s-state at polydiene microstructure formation is indicated. Questions of the polysite mechanism occurrence in complex radical polymerization processes are discussed. A possibility for polymerization to proceed in both free-radical and complex related chain propagation sites is shown.

About the Author

Gennady Zaikov, Yuri Monakov, Natalia Sigaeva, Vadim Urazbaev

"About this title" may belong to another edition of this title.

Store Description

GreatBookPrices.com is your top source for finding new books at the absolute lowest prices, guaranteed ! We offer big discounts - everyday - on millions of titles in virtually any category, from Architecture to Zoology -- and everything in between. Discover great deals and super-savings, on professional books, text book titles, the newest computer guides, or your favorite fiction authors. You'll find it all - at HUGE SAVINGS - at GreatBookPrices. Browse through our complete online product catalog today. Serving customers around the world for years, we help thousands find just the books they're looking for -- at incredibly low, bargain prices.

Visit Seller's Storefront

Seller's business information

Far Corner Europe Limited
19-20 Bourne Court, 19-20 Bourne Court, Woodford Green, IG8 8HD, United Kingdom

Sale & Shipping Terms

Terms of Sale

Company Name: GreatBookPricesUK
Legal Entity: Far Corner Europe Limited
Address: 19-20 Bourne Court, Southend Road, Woodford Green Essex, UK IG8 8HD
Registration #: 10691061
Authorized representative: Danielle Hainsey

Shipping Terms

Our warehouses across the globe are fully operational without substantial delays. We are working hard and continue to overcome the daily challenges presented by COVID-19. There have been reports that delivery carriers are experiencing large delays resulting in longer than normal deliveries to customers. See USPS's website for further detail. We would like to apologize in advance if your item arrives later than the expected delivery due date.

Internal processing of your order will take about 1-2 business days. Please allow an additional 4-14 business days for Media Mail delivery. We have multiple ship-from locations - MD,IL,NJ,UK,IN,NV,TN & GA

Shipping rates from United Kingdom to U.S.A.

Shipping rates from United Kingdom to U.S.A.
Order quantity	10 to 30 business days	10 to 27 business days
First item	US$ 20.08	US$ 20.08

Delivery times are set by sellers and vary by carrier and location. Orders passing through Customs may face delays and buyers are responsible for any associated duties or fees. Sellers may contact you regarding additional charges to cover any increased costs to ship your items.