Proceedings of the NATO Advanced Research Workshop, held in Prague-Pruhonice, Czech Republic, July 4-7, 2000 Editor(s): Centi, Gabriele; Wichterlova, Blanka; Bell, Alexis T. Series: NATO Science Series II. Num Pages: 332 pages, biography. BIC Classification: PNRD. Category: (P) Professional & Vocational; (UP) Postgraduate, Research & Scholarly; (UU) Undergraduate. Dimension: 244 x 170 x 20. Weight in Grams: 1450. . 2001. Hardback. . . . .

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Bibliographic Details

Title: Catalysis by Unique Metal Ion Structures in Solid Matrices
Publisher: Kluwer Academic Publishers
Publication Date: 2001
Language: English
ISBN 10: 0792368746
ISBN 13: 9780792368748
Binding: Hardcover
Condition: New

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Synopsis

Atomically dispersed metal cations and small polyatomic cationic structures co-ordinated to the surface of porous matrices exhibit different properties from the same cationic species contained in a bulk oxide or supported on amorphous carriers. This subject is treated to an extensive review, showing how an understanding of it is essential to the development of a new generation of solid catalysts. There are also exciting opportunities to shape the catalytic properties of the transition metal cations in microporous and mesoporous matrices.
The book covers both theoretical and experimental aspects, including the distribution of framework Al atoms in Si-rich zeolites, distribution and siting of charge-exchanged metal cations, electronic, adsorptive and catalytic properties of metal cations, and correlation of metal cation structure and siting with catalytic activity.

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