Some Complexes of N-Aryl Furfural Nitrones with Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) Chlorides

Language: English

Published by GRIN Verlag, 2013

3656400830 / 9783656400837

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Druck auf Anfrage Neuware - Printed after ordering - Scientific Essay from the year 2011 in the subject Chemistry - Anorganic Chemistry, grade: 3, University of Mosul (DBS), language: English, abstract: Some new metal(II) dichloride complexes with the ligands substituted nitrones of thegeneral formula [ML2Cl2], where M= Co(II), Ni(II), Cu(II), Zn(II) and Cd(II),L=OCH=CHCH=C-CH=N(O)C6H4X (X=H,p-CH3,CH3O,CH3CO,F,Cl,and Br) havebeen prepared and characterized by elemental analysis, IR,1H,13C NMR and Vis/Uvspectroscopy. The IR spectral data showed that the nitrone ligands coordinated withthe metal ion through the most active atom of the N-oxide to give square plannercoordinate (Cu,Ni,) complexes and (Zn,Cd,Co) tetrahedral complexes. No correlationwas observed between the N-O vibrations stretching hing frequency ni(N-O) of thecomplexes and the Hammet (s) constants.

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Title
Some Complexes of N-Aryl Furfural Nitrones with Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) Chlorides
Author
Amer Taqa
Publisher
GRIN Verlag
Publication year
2013
Condition
Neu
Binding
Taschenbuch
Language
English
ISBN 10
3656400830
ISBN 13
9783656400837
Item weight
62 grams
Dimensions
210x148x3 mm

AHA-BUCH GmbH

Einbeck, Germany

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