Some Complexes of N-Aryl Furfural Nitrones with Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) Chlorides

Scientific Essay from the year 2011 in the subject Chemistry - Anorganic Chemistry, grade: 3, University of Mosul (DBS), language: English, abstract: Some new metal(II) dichloride complexes with the ligands substituted nitrones of the general formula [ML2Cl2], where M= Co(II), Ni(II), Cu(II), Zn(II) and Cd(II), L=OCH=CHCH=C-CH=N(O)C6H4X (X=H,p-CH3,CH3O,CH3CO,F,Cl,and Br) have been prepared and characterized by elemental analysis, IR,1H,13C NMR and Vis/Uv spectroscopy. The IR spectral data showed that the nitrone ligands coordinated with the metal ion through the most active atom of the N-oxide to give square planner coordinate (Cu,Ni,) complexes and (Zn,Cd,Co) tetrahedral complexes. No correlation was observed between the N-O vibrations stretching hing frequency ν(N-O) of the complexes and the Hammet (σ) constants.

Amer A. Taqa: Professor at Dental Basic Science, College dentistry, Mosul University, Iraq. Have PhD degree in Dental chemistry. He has published more 100 researches papers in national and international academic journals and authored 22 books. His research interests include dental chemistry, medical chemistry, and inorganic chemistry. He is editorial member in more than 140 international journals. He Nominated as a member of the organizing committees for a number of international and local conferences. E-mail: amertaqa@hotmail.com Publons: https: //publons.com/a/331136 ORCID: http: //orcid.org/0000-0002-3104-0078