Title: Comprehensive Chemical Kinetics: Unimolecular Kinetics, Part 1. The Reaction Step (Volume 39) (Comprehensive Chemical Kinetics, Volume 39)
Publisher: Elsevier Science
Publication Date: 2003
Language: English
ISBN 10: 0444508937
ISBN 13: 9780444508935
Binding: Hardcover
Condition: New

About this title

Synopsis

Unimolecular reactions are in principle the simplest chemical reactions, because they only involve one molecule. The basic mechanism, in which the competition between the chemical reaction step and a collisional deactivation leads to a pressure-dependent coefficient, has been understood for a long time. However, this is a rapidly developing field, and many new and important discoveries have been made in the past decade.

This First Part Part of Two CCK Volumes dealing with Unimolecular Rections, deals with the Reaction Step. The first chapter is an introduction to the whole project, aiming to cover the material necessary to understand the content of the detailed chapters, as well as the history of the development of the area. Chapter 2 is a review of the modern view of the statistical theories, as embodied in the various forms of RRKM theory. Chapter 3 deals with the fully quantum mechanical view of reactive states as resonances.

. Presents considerable advances in the field made during the last decade.. Treats both the statistical as well as the fully quantum mechanical view.

Excerpt. � Reprinted by permission. All rights reserved.

Details important discoveries and advances in unimolecular reactions.

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