First Approaches to Tailor-Made Surfactants and Transition Metal Complexes of Breslow Intermediates

Language: English

Published by Cuvillier Nov 2019, 2019

3736971060 / 9783736971066

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Seller: BuchWeltWeit Ludwig Meier e.K., Bergisch Gladbach, GermanyBuchWeltWeit Ludwig Meier e.K.

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This item is printed on demand - it takes 3-4 days longer - Neuware -Microemulsions are thermodynamically stable, macroscopically isotropic, nanostructured mixtures of at least three components: a polar, a non-polar and an amphiphilic; in general water, oil and surfactant. The surfactant, if optimally selected, generates an ultra-low interfacial tension and a large internal interface. Both properties are of central relevance in this thesis. In the first part, the new fluorescent surfactant class NaCX,YANS was synthesized, comprehensively characterized and first application-relevant studies in the field of cell labeling were carried out. The efficiency ¿ namely the reduction of the interfacial tension ¿ of this new surfactant class was demonstrated at the phase behaviour of non-ionic microemulsions in comparison with common ionic surfactants. As companion product, the highly efficient surfactant class NaCX,YABS was developed, which shows great potential for the independent formation of microemulsions without further co-surfactant. Since microemulsions can completely solubilize hydrophilic and lipophilic components, these systems are outstandingly suitable as reaction medium in organic synthesis across the internal interface. This was closer investigated in decomposition experiments of glucose by an N-heterocyclic carbene (NHC). Moreover, extensive complexation reactions of aldehyde adducts of NHCs (Breslow intermediates) with transition metal compounds provided initial insights into their coordination behaviour. In particular, the high reactivity of cobalt towards Breslow intermediates has been highlighted. 190 pp. Englisch.…

Seller Inventory # 9783736971066

Title
First Approaches to Tailor-Made Surfactants and Transition Metal Complexes of Breslow Intermediates
Author
Tim Schreiner
Publisher
Cuvillier Nov 2019
Publication year
2019
Condition
Neu
Binding
Taschenbuch
Language
English
ISBN 10
3736971060
ISBN 13
9783736971066
Item weight
254 grams
Dimensions
210x148x11 mm

BuchWeltWeit Ludwig Meier e.K.

Bergisch Gladbach, Germany

5-star seller

AbeBooks seller since January 11, 2012

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BuchWeltWeit Ludwig Meier e.K.

Germany