High Resolution Nmr Spectroscopy in Solids ((Nmr Basic Principles and Progr Ess, Volume 11)

Mehring, M.

ISBN 10: 3540077049 / ISBN 13: 9783540077046

Published by Springer-Verlag, 1976

About this Item

Hardback, surplus library copy with usual stampings; reference number taped to spine; light fading, light shelf wear to exterior; corners bumped; cont ents in good condition with clean text, firm binding.

Seller Inventory # 58194

Bibliographic Details

• Title: High Resolution Nmr Spectroscopy in Solids ((Nmr Basic Principles and Progr Ess, Volume 11)
• Publisher: Springer-Verlag
• Publication Date: 1976
• Language: English
• ISBN 10: 3540077049
• ISBN 13: 9783540077046
• Binding: Hardcover
• Condition: Good

About this title

Synopsis

Manipulation and Dilution Tools for Ruling Abundant Species "NMR is dead" was the slogan heard in the late 1960s at least among physicists, until John S. Waugh and his co-workers initiated a series of new NMR experiments, which employed the coherent modulation of interactions by strong radiofrequency fields. A wealth of new phenomena was observed, which are summarized in the introduction for the convenience of the unbiased reader, whereas Section 2 collects the basic spin interactions observed in solids. Line-narrowing effects in dipolar coupled solids by the application of multiple­ pulse experiments are extensively discussed in Section 3. Numerous extensions of the basic Waugh, Huber, and Haeberlen experiment have been developed by different groups and have been applied to the nuclei IH, 9Be, 19F, 27Al, 31p, 63CU in solids. Application of this technique to a variety of systems is still in progress and should reveal interesting insights into weak spin interactions in solids. It was soon realized that rare spins could be used as monitors for molecular fields in the solid state; however, rare spin observation is difficult because of the small signal-to-noise ratio. Pines, Gibby, and Waugh introduced a new concept of cross-polarization, based on ideas of Hahn and co-workers, which allows the detection ofrare spins with increased sensitivity. The dynamics involved are treated in detail. Other sections merely list results obtained by the techniques described and demonstrate their usefulness in the investigation of dynamical problems in molec­ ular and solid state physics.