Much data has been collected from experiments on the kinetics of radical reactions in different solids. This text explores the kinetics of solids. It discusses low-molecular matrices, polymers, and examines hydrogen atom transfer, triple carbene reactions and radical pair transformations. Num Pages: 160 pages, 34 illustrations. BIC Classification: PHFC; PHM; PNRS; TDCP. Category: (P) Professional & Vocational; (UP) Postgraduate, Research & Scholarly; (UU) Undergraduate. Dimension: 247 x 200 x 15. Weight in Grams: 388. . 1998. 1st Edition. Hardcover. . . . . Books ship from the US and Ireland.

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Bibliographic Details

Title: Kinetic Peculiarities of Solid Phase Reactions
Publisher: John Wiley & Sons Inc
Publication Date: 1998
Language: English
ISBN 10: 0471983748
ISBN 13: 9780471983743
Binding: Hardcover
Condition: New

About this title

Synopsis

Much data has been collected from experiments on the kinetios of radical reactions in different solids, but to date, this has not been presented in book format in a thorough and comprehensive way. This book makes the experimental data accessible for all chemists involved in these reactions. Various models of the tunnel atom transfer are analyzed in order to explain the kinetic isotope effect in solid phase reactions and photoinitiated radical reactions are inspected for the kinetic non-equivalence of particles and factors affecting their reactivity.

Topics covered include:

kinetic description of reactions with dispersion particles in reactivity
the influence of space-orientation factors on reactivity in cage reactions
the influence of molecular dynamics on the kinetics of elementary reactions
the effect of structural-physical modification on kinetics of cage radical reactions

About the Author

E. Ya. Davydov is the author of Kinetic Peculiarities of Solid Phase Reactions, published by Wiley.

A. P. Vorotnikov is the author of Kinetic Peculiarities of Solid Phase Reactions, published by Wiley.

G. B. Pariyskii is the author of Kinetic Peculiarities of Solid Phase Reactions, published by Wiley.

G. E. Zaikov is the author of Kinetic Peculiarities of Solid Phase Reactions, published by Wiley.

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