Liquid-Liquid Equilibria of Ternary Systems Using Solvent/Co-Solvent: The Liquid-Liquid Equilibria for pseudo-ternary Systems

Eissa, Hatim M., Al-Dujaili, Amar, Awwad, Akl M.

ISBN 10: 384734711X / ISBN 13: 9783847347118

Published by LAP LAMBERT Academic Publishing, 2012

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Bibliographic Details

• Title: Liquid-Liquid Equilibria of Ternary Systems Using Solvent/Co-Solvent: The Liquid-Liquid Equilibria for pseudo-ternary Systems
• Publisher: LAP LAMBERT Academic Publishing
• Publication Date: 2012
• Language: English
• ISBN 10: 384734711X
• ISBN 13: 9783847347118
• Binding: Paperback
• Condition: Like New
• Book Type: book

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Synopsis

Liquid-liquid equilibrium data of toluene or benzene+n-hexane or n-heptane or n-octane hydrocarbon systems are reported with many solvent mixtures at 298.15K.Complete phase digrams were obtained by evaluating the solubility and tie line results for each ternary mixture. The thermodynamic models :NRTL,UNIQUAC,and UIFAC models were used to correlate the experimental data and to predict the phase compositions of the ternary systems.The NRTL equation fitted the experimental data better than the UNIQUAC and UNIFAC equations:the average root mean square deviations (RMSD) was 0.165 for NRTL as compared to 0.491 for UNIQUAC and 1.304 for UNIFAC.

About the Author

Dr.Hatim M.Eissa has obtained his PhD degree in Chemistry in 2002. He is author of several articles published in reputed journals and is the member of different working groups.