Title: Matrix Isolation Spectroscopy: Proceedings of the NATO Advanced Study Institute: 76 (Nato Science Series C:, 76)
Publisher: Kluwer Academic Publishers
Publication Date: 1981
Language: English
ISBN 10: 9027713286
ISBN 13: 9789027713285
Binding: Book
Edition: 1981st.
Condition: New
Dimensions: 15.6 centimeters width by 3.33 centimeters height by 23.39 centimeters depth

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Synopsis

The matrix isolation (MI) method has now been used for nearly thirty years. During this period it has been actively developed and the range of problems tackled greatly extended. Originally it was used for studies of transient species involv� ing vibrational, electronic and ESR spectroscopy. Nowadays the study of transient species forms a comparatively small part of HI work since it has been amply demonstrated that very fruitful information can be obtained of the structure and interactions of stable molecules and their aggregates. In addition to the s~ectroscopic methods mentioned above the MI technique is nowadays a standard method in research based on vibrational relaxation, luminescence, Mossbauer, magnetic circular dichroism, pulsed NMR and photoelectron spectroscopy. The matrix isolation technique affords considerable advantages over more conventional methods in most applications of spectroscopy. Areas where the technique has been widely applied, or shows great potential, include: metal atom chemistry, and its relation to surface chemistry, high temperature inorganic species, transition metal complexes, interstellar species, free radicals and unstable molecules, conformational studies, molecular com� plexes, and intermolecular forces.

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