Micro and Macro Mixing: Analysis, Simulation and Numerical Calculation (Heat and Mass Transfer)

The homogenization of single phase gases or liquids with chemical reactive components by mixing belongs to one of the oldest basic operations applied in chemical engineering. The mixing process is used as an essential step in nearly all processes of the chemical industry as well as the pharmaceutical and food ind- tries. Recent experimentally and theoretically based results from research work lead to a fairly good prediction of the velocity fields in differend kinds of mixers, where as predictions of simultaneously proceeding homogeneous chemical re- tions, are still not reliable in a similar way. Therefore the design of equipment for mixing processes is still derived from measurements of the so called “mixing time” which is related to the applied methods of measurement and the special - sign of the test equipment itself. The cooperation of 17 research groups was stimulated by improved modern methods for experimental research and visualization, for simulations and nume- cal calculations of mixing and chemical reactions in micro and macro scale of time and local coordinates. The research work was financed for a six years period within the recently finished Priority Program of the German Research Foundation (DFG) named “Analysis, modeling and numerical prediction of flow-mixig with and without chemical reactions (SPP 1141)”. The objective of the investigations was to improve the prediction of efficiencies and selectivities of chemical re- tions on macroscopic scale.

The homogenization of single phase gases or liquids with chemical reactive components by mixing belongs to one of the oldest basic operations applied in chemical engineering. The design of equipment for mixing processes is still derived from measurements of the mixing time which is related to the applied methods of measurement and the special design of the test equipment itself.

This book was stimulated by the Priority Program on "Flow Mixing" financially supported by the Deutsche Forschungsgemeinschaft (DFG). Results are improved modern methods for experimental research and visualization, for simulations and numerical calculations of mixing and chemical reactions in micro and macro scale of time and local coordinates. The results are aimed to improve the prediction of efficiencies and selectivities of chemical reactions in macroscopic scale. The book should give an understanding of the influence of the construction of different mixing equipment on to the momentum, heat and mass transfer as well as reaction processes running on microscopic scales of time and local coordinates.

Newly developed methods of measurement are adjusted to the scales of the selected special transport and conversion processes. They allow a more detailed modeling of the mixing processes by the formulation of an appropriate set of momentum-, heat- and mass balance equations as well as boundary conditions in time and local coordinates together with constitutive equations and reaction kinetics equations as closure laws for numerical and analytical calculations. The improved and more detailed modeling leads to a major progress in predicting mixing processes on the different scales adjusted to transport and reaction processes in molecular, micro- and macro dimensions.