Title: Fe Mossbauer Spectroscopic and Density Functional Theory (DFT) Study On The Interactions of the Metal Ion With Monosaccharides (Materials Science and Technologies)
Publisher: Nova Science Pub Inc
Publication Date: 2011
Language: English
ISBN 10: 1611223016
ISBN 13: 9781611223019
Binding: Soft cover
Condition: New

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Synopsis

The fundamental electrical and magnetic interactions between iron ions and biomaterials were investigated using an experimental approach, 57Fe Mossbauer spectroscopy, and ab initio computational methods. A conventional spin-Hamiltonian approach adopted for the data analysis of the Mossbauer data showed that the metal ion in the Fe-chitosan complex is in the high-spin ferric state and that it has an internal magnetic field of approximately 440 kG, at the nucleus. The magnitude of the internal field arises from the predominant Fermi-contact interaction of the high-spin ferric species with N/O ligands. This book proposes a scheme for the Fe-chitosan complex based on the analysis of the experimental data.

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