New Synthetic Routes to Polyoxometalate Containing Ionic Liquids : An Investigation of their Properties

Sven Herrmann

ISBN 10: 3658087951 / ISBN 13: 9783658087951

Published by Springer Fachmedien Wiesbaden, 2015

About this Item

Druck auf Anfrage Neuware - Printed after ordering - In his Master project Sven Herrmann for the first time carried out fundamental investigations into the development of polyoxometalate based ionic liquids (POM-ILs). The POM-ILs were obtained by charge balancing inorganic polyoxometalate (POM) anions with sterically demanding tetraalkylammonium or tetraalkylphosphonium cations. By functionalization of lacunary Keggin clusters with 3d-transition metals and charge balancing with tetraalkylammonium cations of differing chain length, a model system for the correlation of the molecular structure with macroscopic materials properties was obtained. In a systematic approach the syntheses via self-aggregation is presented. Analytic methods comprise UV-Vis, FTIR, NMR, EPR and Mößbauer spectroscopy. For determination of the materials properties TGA and DSC were carried out and rheological studies shed light onto the flow characteristics of the highly viscous materials.

Seller Inventory # 9783658087951

Bibliographic Details

• Title: New Synthetic Routes to Polyoxometalate Containing Ionic Liquids : An Investigation of their Properties
• Publisher: Springer Fachmedien Wiesbaden
• Publication Date: 2015
• Language: English
• ISBN 10: 3658087951
• ISBN 13: 9783658087951
• Binding: Taschenbuch
• Condition: Neu
• Dimensions: 210W x 148H x 9D millimeters 210 millimeters width by 148 millimeters height by 9 millimeters depth
• Weight: 197 grams

About this title

Synopsis

In his Master project Sven Herrmann for the first time carried out fundamental investigations into the development of polyoxometalate based ionic liquids (POM-ILs). The POM-ILs were obtained by charge balancing inorganic polyoxometalate (POM) anions with sterically demanding tetraalkylammonium or tetraalkylphosphonium cations. By functionalization of lacunary Keggin clusters with 3d-transition metals and charge balancing with tetraalkylammonium cations of differing chain length, a model system for the correlation of the molecular structure with macroscopic materials properties was obtained. In a systematic approach the syntheses via self-aggregation is presented. Analytic methods comprise UV-Vis, FTIR, NMR, EPR and Mößbauer spectroscopy. For determination of the materials properties TGA and DSC were carried out and rheological studies shed light onto the flow characteristics of the highly viscous materials.

About the Author

Sven Herrmann obtained his Masters degree at the University of Erlangen-Nürnberg. He then joined the working group of Prof. Carsten Streb in the inorganic department at the University of Ulm to work on his PhD thesis that targets the development of polyoxometalate based ionic liquids (POM-ILs).