Organometallic Compounds

Language: English

Published by Springer, Springer Feb 2012, 2012

9400957319 / 9789400957312

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This item is printed on demand - Print on Demand Titel. Neuware -A very large number of organo derivatives is formed by the Group IV ele ments silicon, germanium, tin, and lead. In comparing the general properties of these elements, Table 1. 1 shows that the first ionization energies decrease (though not in a regular way) with increase in size and atomic number, con sistent with the general increase in metallic character of the elements. Electro negativity values (which have been the subject of considerable controversy) show no clear trend. Although purely inorganic compounds of tin(n) and leaden) are well known, almost all organo Group IV derivatives show an oxidation state of IV. Bonds to carbon become weaker on passing from silicon to lead, as do the element-element bonds themselves. With any particular element M (M = Si, Ge, Sn, or Pb), there is a small decrease in bond energy in the order: M-Ph > M - Me > M - Et. Although accurate data for organo derivatives are lacking, strengths of bonds to other elements probably decrease in the order: M-F> M-O > M-CI > M-H ~ M-N ~ M-S ~ M-Br > M-I, while for a particular element X, the order is: Si-X > Ge-X > Sn-X > Pb-X. It is therefore understandable that reactions leading to Si-F, Si-O, or Si-CI bonds are especially favoured in a thermodynamic sense.Springer-Verlag KG, Sachsenplatz 4-6, 1201 Wien 540 pp. Englisch.…

Seller Inventory # 9789400957312

Title
Organometallic Compounds
Author
B. J. Aylett
Publisher
Springer, Springer Feb 2012
Publication year
2012
Condition
Neu
Binding
Taschenbuch
Language
English
ISBN 10
9400957319
ISBN 13
9789400957312
Item weight
809 grams
Dimensions
235x155x29 mm

buchversandmimpf2000

Emtmannsberg, BAYE, Germany

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