Organometallic Compounds, Vol. 1: The Main Group Elements, Part 2: Groups 4 and 5

G.E. Coates

ISBN 10: 0412130203 / ISBN 13: 9780412130205

Published by Chapman & Hall, 1979

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Ancien livre de bibliothèque. Edition 1979. Tome 1. Ammareal reverse jusqu'à 15% du prix net de cet article à des organisations caritatives. ENGLISH DESCRIPTION Book Condition: Used, Very good. Former library book. Edition 1979. Volume 1. Ammareal gives back up to 15% of this item's net price to charity organizations.

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Bibliographic Details

• Title: Organometallic Compounds, Vol. 1: The Main Group Elements, Part 2: Groups 4 and 5
• Publisher: Chapman & Hall
• Publication Date: 1979
• Language: English
• ISBN 10: 0412130203
• ISBN 13: 9780412130205
• Binding: Hardcover
• Edition: 4th Edition
• Condition: Très bon

About this title

Synopsis

to thank Messrs J. R. Sanders, W. E. Lindsell and M. G. Swanwick for helping to check the text and references and prepare indexes. Finally, I should like to thank my wife for the very considerable assis­ tance she has given me in the writing and production of this book. M. L. H. G. Contents Preface to the Third Edition, Volume Two Page v INTRODUCTION TO VOLUME TWO I Oassification I The IS-electron rule 2 (i) The basis of the I8-electron rule p. 4, (ii) Exceptions to the I8-electron rule p. 5 1. TWO-ELECTRON LIGANDS 7 A. Classification 7 B. The preparation of olefin-transition metal complexes 7 (a) Displacement of solvent ligands p. 9, (b) Preparations from metal carbonyls p. 9, (c) Less common preparative routes p. 11, Reductive olefination method p. 12 C. A molecular orbital description of the bonding in orga- metallic complexes 13 (a) General comments p. 13, (b) Symmetry considerations p. 13, (c) Energies of the molecular orbitals p. 14 D. A description of the bonding of 2-electron ligands to transition metals 14 E. General comments of 2-electron ligands 19 (a) Infrared studies p. 20, (b) Effect of olefin substituents p. 21, (c) The rotation of ethylene about the ligand-metal bond p. 22, (d) Chemical properties p. 23 F. Particular complexes of metals with 2-electron ligands 25 (a) Copper, silver and gold p. 25, Complexes with benzene p. 28, (b) Nickel, palladium and platinum p.