Organometallic Compounds: Volume One the Main Group Elements Part Two Groups IV and V

Aylett, B. J.:

ISBN 10: 0412130203 / ISBN 13: 9780412130205

Published by Chapman and Hall, 1979

About this Item

521 p. In good condition. The pages are clean and free from markings. Shows slight signs of storage and wear. A withdrawn library copy with the relevant markings. The spine is slightly curled. No dust jacket. Otherwise a decent copy. 9780412130205 Sprache: Englisch Gewicht in Gramm: 1200.

Seller Inventory # 331259

Bibliographic Details

• Title: Organometallic Compounds: Volume One the Main Group Elements Part Two Groups IV and V
• Publisher: Chapman and Hall
• Publication Date: 1979
• Language: English
• ISBN 10: 0412130203
• ISBN 13: 9780412130205
• Binding: Hardcover
• Edition: 4. Edition.
• Seller catalogs:
  • Chemie

About this title

Synopsis

to thank Messrs J. R. Sanders, W. E. Lindsell and M. G. Swanwick for helping to check the text and references and prepare indexes. Finally, I should like to thank my wife for the very considerable assis­ tance she has given me in the writing and production of this book. M. L. H. G. Contents Preface to the Third Edition, Volume Two Page v INTRODUCTION TO VOLUME TWO I Oassification I The IS-electron rule 2 (i) The basis of the I8-electron rule p. 4, (ii) Exceptions to the I8-electron rule p. 5 1. TWO-ELECTRON LIGANDS 7 A. Classification 7 B. The preparation of olefin-transition metal complexes 7 (a) Displacement of solvent ligands p. 9, (b) Preparations from metal carbonyls p. 9, (c) Less common preparative routes p. 11, Reductive olefination method p. 12 C. A molecular orbital description of the bonding in orga- metallic complexes 13 (a) General comments p. 13, (b) Symmetry considerations p. 13, (c) Energies of the molecular orbitals p. 14 D. A description of the bonding of 2-electron ligands to transition metals 14 E. General comments of 2-electron ligands 19 (a) Infrared studies p. 20, (b) Effect of olefin substituents p. 21, (c) The rotation of ethylene about the ligand-metal bond p. 22, (d) Chemical properties p. 23 F. Particular complexes of metals with 2-electron ligands 25 (a) Copper, silver and gold p. 25, Complexes with benzene p. 28, (b) Nickel, palladium and platinum p.