Oxidation kinetics by mild and selective Chromium(VI) complexes | Oxidation kinetics of Chromium(VI) complexes

Dinesh Panday

ISBN 10: 333003520X / ISBN 13: 9783330035201

Published by LAP LAMBERT Academic Publishing, 2020

About this Item

Oxidation kinetics by mild and selective Chromium(VI) complexes | Oxidation kinetics of Chromium(VI) complexes | Dinesh Panday | Taschenbuch | Englisch | 2020 | LAP LAMBERT Academic Publishing | EAN 9783330035201 | Verantwortliche Person für die EU: preigu GmbH & Co. KG, Lengericher Landstr. 19, 49078 Osnabrück, mail[at]preigu[dot]de | Anbieter: preigu.

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Bibliographic Details

• Title: Oxidation kinetics by mild and selective Chromium(VI) complexes | Oxidation kinetics of Chromium(VI) complexes
• Publisher: LAP LAMBERT Academic Publishing
• Publication Date: 2020
• Language: English
• ISBN 10: 333003520X
• ISBN 13: 9783330035201
• Binding: Taschenbuch
• Condition: Neu
• Dimensions: 220W x 150H x 8D millimeters 220 millimeters width by 150 millimeters height by 8 millimeters depth
• Weight: 185 grams
• Seller catalogs:
  • Bücher

About this title

Synopsis

Chromium(VI), in the form of chromic acid and metal dichromates, is a versatile oxidant with some serious disadvantages. Inorganic chromates and dichromates are generally insoluble in most organic solvents and are soluble in water only, whereas most organic compounds are insoluble in water. Therefore, immiscibility is limiting factor in working with inorganic Chromium(VI) compounds. Further, inorganic Cr(VI) oxidants are drastic and less selective. In view of these difficulties, a number of complex chromium derivatives have been prepared and used in synthetic organic chemistry. In view of these difficulties, a number of complex chromium derivatives have been prepared and used in synthetic organic chemistry. Two such derivatives are butyltriphenylphosphonium dichromate (BTPPD) and benzimidazolium dichromate (BIDC). This book is about kinetics and mechanism aspects of the oxidation with these two oxidants.