Specific Intermolecular Interactions of Organic Compounds

Alexei K. Baev

ISBN 10: 3642216218 / ISBN 13: 9783642216213

Published by Springer Berlin Heidelberg, 2012

About this Item

Druck auf Anfrage Neuware - Printed after ordering - Prof. Baev presents in his book the development of the thermodynamic theory of specific intermolecular interactions for a wide spectrum of organic compounds: ethers, ketones, alcohols, carboxylic acids, and hydrocarbons. The fundamentals of an unconventional approach to the theory of H-bonding and specific interactions are formulated based on a concept of pentacoordinate carbon atom. New types of hydrogen bonds and specific interactions are substantiated and on the basis of the developed methodology their energies are determined. The system of interconnected quantitative characteristics of the stability of specific intermolecular interactions is presented. The laws of their transformations are discussed and summarized. The new concept of the extra stabilizing effect of isomeric methyl group on the structure and stability of organic molecules is introduced and the destabilization action on specific interactions is outlined.

Seller Inventory # 9783642216213

Bibliographic Details

• Title: Specific Intermolecular Interactions of Organic Compounds
• Publisher: Springer Berlin Heidelberg
• Publication Date: 2012
• Language: English
• ISBN 10: 3642216218
• ISBN 13: 9783642216213
• Binding: Buch
• Condition: Neu
• Dimensions: 241W x 160H x 29D millimeters 241 millimeters width by 160 millimeters height by 29 millimeters depth
• Weight: 840 grams

About this title

Synopsis

Prof. Baev presents in his book the development of the thermodynamic theory of specific intermolecular interactions for a wide spectrum of organic compounds: ethers, ketones, alcohols, carboxylic acids, and hydrocarbons. The fundamentals of an unconventional approach to the theory of H-bonding and specific interactions are formulated based on a concept of pentacoordinate carbon atoms. New types of hydrogen bonds and specific interactions are substantiated and on the basis of the developed methodology their energies are determined. The system of interconnected quantitative characteristics of the stability of specific intermolecular interactions is presented. The laws of their transformations are discussed and summarized. The new concept of the extra stabilizing effect of isomeric methyl groups on the structure and stability of organic molecules is introduced and the destabilization action on specific interactions is outlined.