State-to-State Dynamical Research in the F+H2 Reaction System

Zefeng Ren

ISBN 10: 3642397557 / ISBN 13: 9783642397554

Published by Springer, 2013

About this Item

State-to-State Dynamical Research in the F+H2 Reaction System | Zefeng Ren | Taschenbuch | Springer Theses | xii | Englisch | 2013 | Springer | EAN 9783642397554 | Verantwortliche Person für die EU: Springer Verlag GmbH, Tiergartenstr. 17, 69121 Heidelberg, juergen[dot]hartmann[at]springer[dot]com | Anbieter: preigu.

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Bibliographic Details

• Title: State-to-State Dynamical Research in the F+H2 Reaction System
• Publisher: Springer
• Publication Date: 2013
• Language: English
• ISBN 10: 3642397557
• ISBN 13: 9783642397554
• Binding: Taschenbuch
• Condition: Neu
• Dimensions: 235W x 155H x 6D millimeters 235 millimeters width by 155 millimeters height by 6 millimeters depth
• Weight: 154 grams
• Seller catalogs:
  • Bücher

About this title

Synopsis

This thesis addresses two important and also challenging issues in the research of chemical reaction dynamics of F+H2 system. One is to probe the reaction resonance and the other is to determine the extent of the breakdown of the Born-Oppenheimer approximation (BOA) experimentally. The author introduces a state-of-the-art crossed molecular beam-scattering apparatus using a hydrogen atom Rydberg "tagging" time-of-flight method, and presents thorough state-to-state experimental studies to address the above issues. The author also describes the observation of the Feshbach resonance in the F+H2 reaction, a precise measurement of the differential cross section in the F+HD reaction, and validation of a new accurate potential energy surface with spectroscopic accuracy. Moreover, the author determines the reactivity ratio between the ground state F(2P3/2) and the excited state F*(2P1/2) in the F+D2 reaction, and exploits the breakdown of BOA in the low collision energy.