Syntheses, Structures and Properties of FeIII-LnIII Complexes using N-substituted Diethanolamine Ligands

Language: English

Published by Cuvillier, Cuvillier Dez 2014, 2014

3954048809 / 9783954048809

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This item is printed on demand - Print on Demand Titel. Neuware -In this thesis, N-substituted diethanolamine ligands have been employed in the syntheses of heterometallic FeIII-LnIII clusters. The reactions of a preformed [FeIII3O]7+ benzoate triangle, LnIII salts and the ligands in different solvents under normal or solvothermal conditions lead to several mixed FeIII-LnIII species with different topologies. Furthermore, new species stabilized under solvothermal conditions can be obtained via a solvothermal treatment of the FeIII-LnIII compounds which result from reactions conducted under normal conditions. The resulting compounds were structurally analyzed by single-crystal X-ray crystallography and X-ray powder diffraction. The magnetic properties and spectroscopic studies were investigated using magnetic susceptibility measurements and Mössbauer spectroscopy. Magnetic studies reveal that three analogous hexanuclear {FeIII4DyIII2} compounds as well as a {FeIII7DyIII4} compound display single molecule magnet behavior.Cuvillier Verlag, Nonnenstieg 8, 37075 Göttingen 162 pp. Englisch.…

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Title
Syntheses, Structures and Properties of FeIII-LnIII Complexes using N-substituted Diethanolamine Ligands
Author
Sihuai Chen
Publisher
Cuvillier, Cuvillier Dez 2014
Publication year
2014
Condition
Neu
Binding
Taschenbuch
Language
English
ISBN 10
3954048809
ISBN 13
9783954048809
Item weight
219 grams
Dimensions
210x148x9 mm

buchversandmimpf2000

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