Synthesis, Characterization & Application Of Mn(III) Complex Compound: Mn (III)

Gudden, Seema, Yadava, Sudha, Yadava, Umesh

ISBN 10: 3659130044 / ISBN 13: 9783659130045

Published by LAP LAMBERT Academic Publishing, 2012

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Bibliographic Details

• Title: Synthesis, Characterization & Application Of Mn(III) Complex Compound: Mn (III)
• Publisher: LAP LAMBERT Academic Publishing
• Publication Date: 2012
• Language: English
• ISBN 10: 3659130044
• ISBN 13: 9783659130045
• Binding: Paperback
• Condition: Like New
• Book Type: book

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Synopsis

Manganese has variable oxidation states and appears as Mn(III) with redox function. It plays an important role in numerous biological processes associated with utilization or generation of hydrogen peroxide or dioxygen. The functions of these type are known viz manganese superoxide dismutase, manganese catalase , manganese peroxidase, manganese ribonucleotide reductase and oxygen involving complex in photo system-II. This has prompted to under take the coordination of Mn(III) ions with ligands. The oxygen donar ligands used for the coordination are β-diketones since β-diketones anions are powerful chelating species and they give stable Mn(III) complex which can further be used for preparing other Mn(III) species that can be used as catalysts. The tris (β-diketonate) Mn(III) complex gives substitution as well as addition reactions with other ligands. Here nitrogen donar ligands used are ethylenediamine, propylenediamine and hexamethylenediamine. The nitrogen donar atom ligands ultimately result in the mixed ligand complexes for Mn(III) which are more stable in this oxidation state of manganese. In this way the aim of preparing stable Mn(III) complexes is achieved by the oxygen donor

About the Author

Dr. Seema , working as Patent Examiner at Indian Patent Office, New Delhi, is Ph.D from DDU Gorakhpur University, Gorakhpur. Dr. Sudha Yadava Associate Professor currently Associate . Prof., Dept of Chemistry, Same University.Dr. Umesh. Yadava, a recipient of DST young Scientist Award, is currently Assit. Prof., Dept of Physics, Same University.