Three-Dimensional Free-Radical Polymerization

Language: English

Published by Springer Berlin Heidelberg, Springer Berlin Heidelberg Okt 2010, 2010

3642099580 / 9783642099588

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This item is printed on demand - Print on Demand Titel. Neuware -At present, three-dimensional free-radical polymerization (TFRP) is a special eld of radical polymerization. TFRP is characterized by speci c kinetic regularities and mechanisms of processes for the formation of cross-linked or hyper-branched po- mers, and they are different from the kinetics and mechanism of classical radical polymerization. The fundamental studies of kinetics and mechanism of TFRP with formation of cross-linked polymers have been carried out in three stages. The rst stage lasted from 1960 until 1983, and the main mechanisms of TFRP of oligo(acrylates) were established during this stage [1¿3]. Condensation telomerization, being a universal oligo(acrylate) synthesis procedure, allows us to vary certain molecular parameters, such as length and exibility of oligomeric blocks, number and type of reactive groups (methacrylic or acrylic groups), and chemical nature of atomic groups of an oligomeric block, which represent the centers of strong intermolecular interactions. For this reason, oligo(acrylates) were very convenient compounds for establi- ing the main kinetic regularities of TFRP and regularities of formation of polymer three-dimensional cross-linkedstructures,according totheso-calledmicrohetero- neous mechanism (G.V. Korolev, 1977), at the topological and morphological levels.Springer Verlag GmbH, Tiergartenstr. 17, 69121 Heidelberg 288 pp. Englisch.

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Title
Three-Dimensional Free-Radical Polymerization
Author
Michael Mogilevich
Publisher
Springer Berlin Heidelberg, Springer Berlin Heidelberg Okt 2010
Publication year
2010
Condition
Neu
Binding
Taschenbuch
Language
English
ISBN 10
3642099580
ISBN 13
9783642099588
Item weight
441 grams
Dimensions
235x155x16 mm

buchversandmimpf2000

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