"Studies on Polymerization and Ring Formation I" in An Introduction to the General Theory of Condensation Polymers The Journal of the American Chemical Society. p. 2548 August, 1929 Vol 51 No. 8

Carothers, Wallace H.

Published by JACS, 1929

About this Item

KEY POLYMERIZATION ARTICLE BY FATHER OF NYLON. In August 1929, the Journal of the American Chemical Society published "Studies on Polymerization and Ring Formation. I. An Introduction to the General Theory of Condensation Polymers" by Wallace H. Carothers. This seminal paper laid the foundation for the modern understanding of condensation polymerization. Key Contributions: (1) Condensation Polymerization Theory: Carothers introduced a comprehensive theory explaining how monomers combine through condensation reactions, releasing small molecules like water, to form polymers. (2) Degree of Polymerization: He elucidated the concept of the degree of polymerization, detailing how the average number of monomer units in a polymer chain affects its molecular weight and properties. (3) Ring Formation vs. Linear Chains: The study examined the competition between linear polymer chain growth and the formation of cyclic structures, analyzing factors that influence whether a polymerization process yields long chains or ring compounds. (4) Kinetics and Mechanisms: Carothers provided insights into the reaction kinetics and mechanisms governing condensation polymerizations, offering a framework that would guide future research in polymer chemistry. The establishment of modern polymer science by Wallace Carothers and the first nylon plant, built by DuPont, at Seaford, are two deeply interwoven National Historic Chemical Landmarks. The research of Carothers not only confirmed the existence of molecules of extremely high molecular weight, but led as well to the development of nylon, the first totally synthetic fiber used in consumer products.

Seller Inventory # EBS100224

Bibliographic Details

• Title: "Studies on Polymerization and Ring Formation I" in An Introduction to the General Theory of Condensation Polymers The Journal of the American Chemical Society. p. 2548 August, 1929 Vol 51 No. 8
• Publisher: JACS
• Publication Date: 1929
• Binding: Hardcover
• Edition: 1st Edition.
• Condition: Very Good
• Dust Jacket Condition: No Jacket
• Seller catalogs:
  • Chemistry