Explore the quantum view of how chemical reactions get started and how rates are determined.
This edition presents a focused look at activated states, transition probabilities, and the role of vibrational energy in reaction dynamics. It blends theory with a practical formulation that helps readers grasp how quantum mechanics shapes everyday chemical processes.
The book explains how the activated state (ABC) is treated as a vibrationally excited quantum system near a saddle point on the potential energy surface. It shows how to frame the rate problem in terms of perturbation theory, energy levels, and transition probabilities, and it discusses the limitations of classical views for light-atom systems. You’ll see how activation energy can differ from a simple energy barrier when quantum effects are considered, and why a careful quantum approach matters for accurate predictions."synopsis" may belong to another edition of this title.
Seller: Forgotten Books, London, United Kingdom
Paperback. Condition: New. Print on Demand. This book delves into the quantum theory of chemical reactions between lightweight atoms or molecules. In contrast to the traditional statistical theory, which often treats these reactions classically, the author presents a quantum-mechanical approach based on the latest scientific understandings of energy states, potential energy functions, and wave mechanics. The author argues that many of the assumptions made by the traditional approach, while valuable for qualitative explanations, are insufficient for making accurate quantitative predictions. This book offers a deeper understanding of the nature and mechanisms of chemical reactions at the quantum level, providing a valuable tool for researchers, students, and anyone interested in the fundamental principles of these processes. This book is a reproduction of an important historical work, digitally reconstructed using state-of-the-art technology to preserve the original format. In rare cases, an imperfection in the original, such as a blemish or missing page, may be replicated in the book. print-on-demand item. Seller Inventory # 9781330006382_0
Quantity: Over 20 available
Seller: PBShop.store US, Wood Dale, IL, U.S.A.
PAP. Condition: New. New Book. Shipped from UK. Established seller since 2000. Seller Inventory # LW-9781330006382
Seller: PBShop.store UK, Fairford, GLOS, United Kingdom
PAP. Condition: New. New Book. Shipped from UK. Established seller since 2000. Seller Inventory # LW-9781330006382
Quantity: 15 available