Compounds with Sulfur of Oxidation Number II (Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition) - Hardcover

Baumann, Norbert; Fachmann, Hans-Jürgen; Jotter, Reimund

Hardcover

ISBN 10: 3540937072 ISBN 13: 9783540937074

Publisher: Springer, 1994

Synopsis

This volume continues the description of acyclic sulfur(II)-nitrogen compounds with two-coordinate sulfur. N,N,N',N'-Tetraorganyl-substituted diaminosulfanes are generally prepared by reacting secondary amines with SCl2. N,N,N',N'-Tetraalkyl-diamino-sulfanes form adducts with boron compounds and complexes with transition metals. Carbon disulfide and various reagents of the X=C=Y type can be readily inserted into the S-N bonds. R2NSNR2 is reacted with CS2 to give R2NC(S)-Sn-C(S)NR2, n z 2. Reactions of R2NSNR2 with isocyanate and isothiocyanate, R'N=C=Y (Y = O,S), produce R2NSN(R')C(Y)NR2. The biological activity of diaminosulfanes with the appropriate substituents (e.g., R-OC(O), R = 2,2-dimethyl-2,3-dihydro-7-yl-benzofuran) has been explored.

Edition details

• Publisher: Springer
• Publication date: 1994
• Language: English
• ISBN 10: 3540937072
• ISBN 13: 9783540937074
• Binding: Hardcover
• Number of pages: 297
• Editor: Kubny Alfons, Baumann Norbert, Fachmann Hans-Jürgen, Jotter Reimund