Gmelin Handbook of Inorganic Chemistry. System Number 9: S Sulfur-Nitrogen-Compounds. Part 6: Compounds with Sulfur of Oxidation Number IV.

Gmelin-Institut für Anorg. Chemie der Max-Planck-Gesellschaft zur Förderung d. Wissensch. (Hg):

ISBN 10: 3540936092 / ISBN 13: 9783540936091

Published by Berlin, Springer Vlg., 1990

About this Item

330 S. Very good condition. In slip case. Sprache: Englisch Gewicht in Gramm: 990.

Seller Inventory # 625073

Bibliographic Details

• Title: Gmelin Handbook of Inorganic Chemistry. System Number 9: S Sulfur-Nitrogen-Compounds. Part 6: Compounds with Sulfur of Oxidation Number IV.
• Publisher: Berlin, Springer Vlg.
• Publication Date: 1990
• Language: English
• ISBN 10: 3540936092
• ISBN 13: 9783540936091
• Binding: Hardcover/Pappeinband
• Edition: 8th ed.
• Weight: 990 grams
• Seller catalogs:
  • Chemie

About this title

Synopsis

This volume continues the description of acyclic sulfur(II)-nitrogen compounds with two-coordinate sulfur. N,N,N',N'-Tetraorganyl-substituted diaminosulfanes are generally prepared by reacting secondary amines with SCl2. N,N,N',N'-Tetraalkyl-diamino-sulfanes form adducts with boron compounds and complexes with transition metals. Carbon disulfide and various reagents of the X=C=Y type can be readily inserted into the S-N bonds. R2NSNR2 is reacted with CS2 to give R2NC(S)-Sn-C(S)NR2, n z 2. Reactions of R2NSNR2 with isocyanate and isothiocyanate, R'N=C=Y (Y = O,S), produce R2NSN(R')C(Y)NR2. The biological activity of diaminosulfanes with the appropriate substituents (e.g., R-OC(O), R = 2,2-dimethyl-2,3-dihydro-7-yl-benzofuran) has been explored.