Gmelin Handbook of Inorganic Chemistry. System Number 9: S Sulfur-Nitrogen-Compounds. Part 5: Compounds with Sulfur of Oxidation Number IV.

Gmelin-Institut für Anorg. Chemie der Max-Planck-Gesellschaft zur Förderung d. Wissensch. (Hg):

ISBN 10: 3540935991 / ISBN 13: 9783540935995

Published by Berlin, Springer Vlg., 1990

About this Item

276 S. Very good condition. In slip case. Sprache: Englisch Gewicht in Gramm: 865.

Seller Inventory # 625072

Bibliographic Details

• Title: Gmelin Handbook of Inorganic Chemistry. System Number 9: S Sulfur-Nitrogen-Compounds. Part 5: Compounds with Sulfur of Oxidation Number IV.
• Publisher: Berlin, Springer Vlg.
• Publication Date: 1990
• Language: English
• ISBN 10: 3540935991
• ISBN 13: 9783540935995
• Binding: Hardcover/Pappeinband
• Edition: 8th ed.
• Weight: 865 grams
• Seller catalogs:
  • Chemie

About this title

Synopsis

The present volume is the first of a series describing acyclic sulfur-nitrogen compounds with sulfur of oxidation number IV. The acyclic sw-N compounds are arranged according to the coordination number of the sulfur. Neutral compounds are described before ions and complex compounds. The preceding series "Sulfur-Nitrogen Compounds" Parts 2, 3, and 4 covers the cyclic sw-N compounds. In this volume, the first section deals with sulfur-nitrogen compounds with 1-coordinate sulfur and begins with the sulfur nitride {thiazyl) radical, SN. This transient molecule was observed in its electronic ground state and several electronically excited states. The descrip­ tions of the sulfur nitride (thiazyl) ions SN+ and SW follow. The SN+ ionwas studied in the gas phase as weil as in the solid state where it forms salts. Thionitrosyl complexes containing the SN Iigand as a terminal linear unit are described at the end of the first section. The second section concerns Sulfur-nitrogen compounds with 2-coordinate sulfur and starts with the description of poly(sulfur nitride), (SNlx· The preparation, crystal structure, and metallic and superconducting properties of (SN)x, which were extensively studied, fill a !arge part of the volume. Halogen-modified poly(sulfur nitride) such as the widely studied (SNBr )x 04 and Na-modified poly(sulfur nitride) are dealt with in the following chapters.