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This book provides the broad scientific readership with a comprehensive summary and critical overview of a topic in organometallic chemistry. A wide variety of catalytic functionalization reactions of C-H bonds by the utilization of a chelation have been developed recently and are comprehensively discussed in this book by leading experts. In addition, new approaches to directed hydrometalation and directed carbometalation as a key step are also discussed.
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"This volume provides summaries of transition metal catalyzed reactions where a directed metalation is involved. ... Chatani has compiled seven reviews that are written by experts in the field, are heavily referenced, and are amply illustrated. This work also contains a subject index for this volume and an author index for all 24 volumes in the series. Summing Up: Recommended. Graduate students through professionals." (J. Landesberg, CHOICE, Vol. 45 (10), June, 2008)
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- PublisherSpringer
- Publication date2010
- ISBN 10 3642094937
- ISBN 13 9783642094934
- BindingPaperback
- Number of pages218
- EditorChatani Naoto
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Directed Metallation
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Directed Metallation (Topics in Organometallic Chemistry) [Paperback ]
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Directed Metallation
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Book Description Taschenbuch. Condition: Neu. Druck auf Anfrage Neuware - Printed after ordering - Directed metalation is recognized as one of the most useful methodologies for the regio- and stereoselective generation of organometallic species, the generation of which necessarily leads to the selective formation of organic products. Cyclometalation using Li, Mn, and Pd, and directed hydrometalation and carbometalation using Al and Zn, have been utilized for regio- and/or stereoselective synthesis for decades. Recently, a new chelation-assisted methodology has been developed not only for controlling regio- and stereoselectivity of reactions, but also for accelerating reactions. In particular, chelation-methodology has been utilized as a new activation method, in which a carbon-metal bond is generated directly from a C-H bond; a reaction rarely achieved using conventional methods. A wide variety of catalytic functionalization reactions of C-H bonds by the utilization of a chelation, have been developed recently and are comprehensively discussed in this book by leading experts. In addition, new approaches to directed hydrometalation and directed carbometalation as a key step are also discussed. A unique stereo- and regioselective hydroformylation has been developed through the utilization of directed hydrometalation. The regioselective Mizoroki-Heck reaction is another example in which directed carbometalation can be used to achieve a high regioselectivity. These examples emphasize how these innovative methodologies are contributing to different fields of chemistry. Seller Inventory # 9783642094934
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Directed Metallation (Topics in Organometallic Chemistry, 24)
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Book Description Condition: New. Dieser Artikel ist ein Print on Demand Artikel und wird nach Ihrer Bestellung fuer Sie gedruckt. Provides the broad scientific readership with comprehensive summary and critical overview of a topic in organometallic chemistryResearch in this rapidly developing transdisciplinary field is having profound influence on other areas of scientific i. Seller Inventory # 5048503
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Book Description Condition: New. pp. 220. Seller Inventory # 2614417971
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Directed Metallation
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Book Description Taschenbuch. Condition: Neu. This item is printed on demand - it takes 3-4 days longer - Neuware -This book provides the broad scientific readership with a comprehensive summary and critical overview of a topic in organometallic chemistry. A wide variety of catalytic functionalization reactions of C-H bonds by the utilization of a chelation have been developed recently and are comprehensively discussed in this book by leading experts. In addition, new approaches to directed hydrometalation and directed carbometalation as a key step are also discussed. 220 pp. Englisch. Seller Inventory # 9783642094934
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Book Description Condition: New. Print on Demand pp. 220 170 Illus. Seller Inventory # 11255788
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Directed Metallation (Topics in Organometallic Chemistry)
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Book Description Paperback. Condition: Brand New. 218 pages. 9.25x6.10x0.50 inches. In Stock. Seller Inventory # x-3642094937
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