The Polybasic Acids of Mesitylene (Classic Reprint) - Hardcover

Mary Bidwell Breed

9780266964209: The Polybasic Acids of Mesitylene (Classic Reprint)

Hardcover

ISBN 10: 0266964206 ISBN 13: 9780266964209

Publisher: Forgotten Books, 2018

View all copies of this ISBN edition

0 Used

2 New

From US$ 38.02

Uncover the chemistry of a rich, less-explored family of acids.

This study delves into the polybasic acids derived from mesitylene, revealing how chemists approached adding carboxyl groups to a complex aromatic nucleus. The work traces historical attempts, key insights, and the experimental paths chosen to build and analyze these unusual acids.

The book describes the rationale for focusing on di-ortho-substituted substrates, discusses the challenges and strategies of introducing carboxyl groups, and presents the preparation and isolation of specific mesitylene acids. It covers methods of oxidation, esterification, and salt formation, and reports observations on conductivity, dissociation, and the behavior of related derivatives. The discussion weaves together qualitative findings and quantitative data to illustrate how di-ortho substitution affects reactivity and utility in this area of organic chemistry.

Historical context and the problem space around polybasic acids of aromatic hydrocarbons.
Experimental approaches to form and oxidize di-orthosubstituted intermediates.
Characterization details, including crystal forms, melting points, and salt behavior.
Insights into ester formation, saponification, and conductivity measurements.

Ideal for readers of historical and experimental organic chemistry, this edition provides a window into early 20th-century methods and the careful reasoning behind them.

"synopsis" may belong to another edition of this title.