Excerpt from Compound Formation, Solubility, and Ionization in Fused Salt Mixtures: Compound Formation Between Aluminium Bromide, and Other Bromides
In a recent series of papers by Kendall and his coworkers1 extensive evidence has been presented correlating compound forma tion, solubility, and ionization in solution. It has been postulated that compound formation is most marked and consequently solubility is most extensive in systems where the radicals are most diverse in character; the criterion of diversity being their position in the electrode potential series. Thus Landon2 and Davidson3 found in the systems sulfuric acid-metal sulfate that potassium and silver, the metals farthest removed from hydrogen in either direction, gave the greatest compound formation. This diversity rule has been tested for a large number of systems and has been found to hold Without marked exception. A few minor discrepancies, however, have come to light; and in order to explain these, several additional factors, such as atomic volume, internal pressure, and unsaturation, which will be taken up more fully below, have been mentioned.
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Paperback. Condition: New. Print on Demand. This book delves into the fascinating world of fused salt mixtures, exploring the complex interactions that occur when different salts are combined at high temperatures. The author meticulously investigates the formation of double salts, or compounds formed when two salts combine, in a series of experiments using aluminium bromide as a solvent. Building upon the pioneering work of Kendall and his colleagues, the author explores the ââ Ëdiversity ruleââ ⢠ââ â the principle that compound formation and solubility are most pronounced when the constituent radicals of the salts are chemically diverse. This principle, however, is not a universal rule, and the author explores additional factors that influence compound formation and solubility, including atomic volume, internal pressure, and unsaturation. The book documents the identification of 32 new compounds, meticulously charting the effects of the aforementioned factors through meticulous analysis of the freezing points of numerous salt mixtures. Ultimately, this book offers valuable insights into the complex interplay of factors that govern compound formation and solubility in fused salt mixtures, significantly advancing our understanding of this critical area of chemistry. This book is a reproduction of an important historical work, digitally reconstructed using state-of-the-art technology to preserve the original format. In rare cases, an imperfection in the original, such as a blemish or missing page, may be replicated in the book. print-on-demand item. Seller Inventory # 9781332351510_0
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